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The effect of the tert-butyl group on the progress of a chemical reaction is called the Thorpe–Ingold effect illustrated in the Diels-Alder reaction below. Compared to a hydrogen substituent, the tert-butyl substituent accelerates the reaction rate by a factor of 240. [2] tert-Butyl effect. The tert-butyl effect is an example of steric hindrance.
tert-Butyl alcohol is the simplest tertiary alcohol, with a formula of (CH 3) 3 COH (sometimes represented as t -BuOH). Its isomers are 1-butanol, isobutanol, and butan-2-ol. tert -Butyl alcohol is a colorless solid, which melts near room temperature and has a camphor -like odor. It is miscible with water, ethanol and diethyl ether.
Butanol (also called butyl alcohol) is a four-carbon alcohol with a formula of C 4 H 9 O H, which occurs in five isomeric structures (four structural isomers), from a straight-chain primary alcohol to a branched-chain tertiary alcohol; [1] all are a butyl or isobutyl group linked to a hydroxyl group (sometimes represented as BuOH, sec-BuOH, i-BuOH, and t-BuOH).
The terms sec and tert are considered obsolete and should only be used for unsubstituted sec-butoxy, sec-butyl [26] [27] or tert-butyl groups. [ 28 ] [ 27 ] There are various spellings such as "sec-butyl", "s-butyl", "sBu" or "bus" which are also considered obsolete.
Butan-2-ol, or sec-butanol, is an organic compound with formula C H 3 CH (O H)CH 2 CH 3. Its structural isomers are 1-butanol, isobutanol, and tert -butanol. 2-Butanol is chiral and thus can be obtained as either of two stereoisomers designated as (R)- (−)-butan-2-ol and (S)- (+)-butan-2-ol. It is normally encountered as a 1:1 mixture of the ...
Infobox references. tert-Butyl isocyanide is an organic compound with the formula Me 3 CNC (Me = methyl, CH 3). It is an isocyanide, commonly called isonitrile or carbylamine, as defined by the functional group C≡N-R. tert -Butyl isocyanide, like most alkyl isocyanides, is a reactive colorless liquid with an extremely unpleasant odor.
Isobutylamine is an organic chemical compound (specifically, an amine) with the formula (CH 3) 2 CHCH 2 NH 2, and occurs as a colorless liquid. [1][2] Isobutylamine is one of the four isomeric amines of butane, the others being n -butylamine, sec -butylamine and tert -butylamine. It is the decarboxylated form of the amino acid valine, and the ...
Butyl butyrate, or butyl butanoate, is an organic compound that is an ester formed by the condensation of butyric acid and n -butanol. It is a clear, colorless liquid that is insoluble in water, but miscible with ethanol and diethyl ether. Its refractive index is 1.406 at 20 °C.