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In quantum physics and chemistry, quantum numbers are quantities that characterize the possible states of the system. To fully specify the state of the electron in a hydrogen atom, four quantum numbers are needed. The traditional set of quantum numbers includes the principal, azimuthal, magnetic, and spin quantum numbers. To describe other ...
The term "azimuthal quantum number" was introduced by Arnold Sommerfeld in 1915 [1]: II:132 as part of an ad hoc description of the energy structure of atomic spectra. . Only later with the quantum model of the atom was it understood that this number, ℓ, arises from quantization of orbital angular moment
Each orbital in an atom is characterized by a set of values of three quantum numbers n, ℓ, and m ℓ, which respectively correspond to electron's energy, its orbital angular momentum, and its orbital angular momentum projected along a chosen axis (magnetic quantum number). The orbitals with a well-defined magnetic quantum number are generally ...
In atomic physics, a term symbol is an abbreviated description of the total spin and orbital angular momentum quantum numbers of the electrons in a multi-electron atom.So while the word symbol suggests otherwise, it represents an actual value of a physical quantity.
The classical definition of angular momentum is =.The quantum-mechanical counterparts of these objects share the same relationship: = where r is the quantum position operator, p is the quantum momentum operator, × is cross product, and L is the orbital angular momentum operator.
s = spin quantum number; m s = spin magnetic quantum number; ℓ = Azimuthal quantum number; m ℓ = azimuthal magnetic quantum number; j = total angular momentum quantum number; m j = total angular momentum magnetic quantum number
Therefore, the term with lowest energy is also the term with maximum and maximum number of unpaired electrons with equal spin angular momentum (either +1/2 or -1/2). For a given multiplicity, the term with the largest value of the total orbital angular momentum quantum number has the lowest energy.
Other magnetic quantum numbers are similarly defined, such as m j for the z-axis component the total electronic angular momentum j, [1] and m I for the nuclear spin I. [2] Magnetic quantum numbers are capitalized to indicate totals for a system of particles, such as M L or m L for the total z-axis orbital angular momentum of all the electrons ...