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Copper(II) chlorate is a chemical compound of the transition metal copper and the chlorate anion with basic formula Cu(ClO 3) 2. Copper chlorate is an oxidiser. [5] It commonly forms the tetrahydrate, Cu(ClO 3) 2 ·4H 2 O.
A 2010 study has discovered the presence of natural chlorate deposits around the world, with relatively high concentrations found in arid and hyper-arid regions. [2] The chlorate was also measured in rainfall samples with the amount of chlorate similar to perchlorate. It is suspected that chlorate and perchlorate may share a common natural ...
Magnesium perchlorate is a powerful oxidizing agent, with the formula Mg(ClO 4) 2. The salt is also a superior drying agent for gas analysis. Magnesium perchlorate decomposes at 250 °C. [2] The heat of formation is -568.90 kJ/mol. [3] The enthalpy of solution is quite high, so reactions are done in large amounts of water to dilute it.
Ca(ClO 3) 2 + 2 KCl → 2 KClO 3 + CaCl 2. This is the second step of the Liebig process for the manufacture of potassium chlorate. [2] Solutions of calcium chlorate react with solutions of alkali carbonates to give a precipitate of calcium carbonate and the alkali chlorate in solution: Ca(ClO 3) 2 + Na 2 CO 3 → 2 NaClO 3 + CaCO 3
These dichlorides exist in both polymeric, or "α", and hexameric, or "β" structures. The β form converts to the α form at 500 °C. In the β form, the Pt-Pt distances are 3.32–3.40 Å, indicative of some bonding between the pairs of metals. In both forms of PtCl 2, each Pt center is four-coordinate, being surrounded by four chloride ligands.
In cis-bis(triphenylphosphine)platinum chloride, the average Pt-P has a bond distance of 2.261 Å and the average Pt-Cl has a bond distance of 2.346 Å. [2] In trans-bis(triphenylphosphine)platinum chloride, the Pt-P distance is 2.316 Å and the Pt-Cl distance is 2.300 Å. [1] The complex also undergoes photoisomerization.
Manganese(II) chlorate is an unstable chemical compound with the formula Mn(ClO 3) 2. It is unstable even in dilute solution. As a hexahydrate, it is solid below −18°C. Above this it melts, to form an extremely explosive pink liquid. [2]
The hexahydrate Mg(ClO 3) 2 ·6H 2 O decomposes to the tetrahydrate at 35 °C. At 65 °C, it dehydrates to the dihydrate, then at 80 °C forms a basic salt. If further heated to 120 °C it decomposes to water, oxygen, chlorine, and magnesium oxide. [2] As confirmed by X-ray crystallography, the di- and hexahydrates feature octahedral Mg 2 ...