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Zonochlorite is a misnomer sometimes given rounded masses of chlorastrolite within or weathered out of amygdaloidal cavities, especially those from the area around Nipigon Bay (on Lake Superior), Ontario, Canada. Confusion may derive from the fact that zonochlorite is sold as faux chlorastrolite.
It can be formed by treating zirconium tetrachloride with dichlorine hexoxide-perchloric acid mixture at −35 °C. [1]Zirconium perchlorate reacts irreversibly with most organic compounds but is inert towards carbon tetrachloride, chloroformide.
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