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The Corey–Itsuno reduction, also known as the Corey–Bakshi–Shibata (CBS) reduction, is a chemical reaction in which a prochiral ketone is enantioselectively reduced to produce the corresponding chiral, non-racemic alcohol. The oxazaborolidine reagent which mediates the enantioselective reduction of ketones was previously developed by the ...
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Organic redox reaction. Identifiers. Organic Chemistry Portal. luche-reduction. RSC ontology ID. RXNO:0000286. Luche reduction is the selective organic reduction of α,β-unsaturated ketones to allylic alcohols. [1] [2] [3] The active reductant is described as "cerium borohydride", which is generated in situ from NaBH 4 and CeCl 3 (H 2 O) 7. [4]
Keto acid. In organic chemistry, keto acids or ketoacids (also called oxo acids or oxoacids) are organic compounds that contain a carboxylic acid group ( −COOH) and a ketone group ( >C=O ). [1] In several cases, the keto group is hydrated. The alpha-keto acids are especially important in biology as they are involved in the Krebs citric acid ...