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Kevlar (para-aramid) [2] is a strong, heat-resistant synthetic fiber, related to other aramids such as Nomex and Technora. Developed by Stephanie Kwolek at DuPont in 1965, [ 3 ] [ 2 ] [ 4 ] the high-strength material was first used commercially in the early 1970s as a replacement for steel in racing tires.
Terephthaloyl chloride (TCL, 1,4-benzenedicarbonyl chloride) is the acyl chloride of terephthalic acid.It is a white solid at room temperature. It is one of two precursors used to make Kevlar, the other being p-phenylenediamine.
Aramid fibers, short for aromatic polyamide, are a class of heat-resistant and strong synthetic fibers. They are used in aerospace and military applications, for ballistic-rated body armor fabric and ballistic composites, in marine cordage , marine hull reinforcement, as an asbestos substitute, [ 1 ] and in various lightweight consumer items ...
Excellent thermal stability at temperature extremes, water repellency, chemical stability and resistance to petroleum products have made Kevlar KM2 an indispensable asset to the military personnel who use it every day." [1] "Kevlar KM2 fiber is a transversely isotropic material. Its tensile stress–strain response in the axial direction is ...
In 1966, Stephanie Kwolek, a chemist working for E.I. DuPont de Nemours & Co., developed Kevlar; a strong, lightweight liquid polymer that can be spun into a fiber and woven into cloth. [3] Kevlar was initially used as a replacement for steel-belting in tires, and later for use in ropes, gaskets, and automotive and aviation parts.
The polymer is closely related to Teijin Aramids's Twaron or DuPont's Kevlar. Technora is derived from two different diamines, 3,4'-ODA and PPD, whereas Twaron is derived from PPD alone. Because only one amide solvent is used in this very straightforward procedure, spinning can be completed immediately after polymer synthesis.
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In contrast, Kevlar derives its strength from strong bonding between relatively short molecules. The weak bonding between olefin molecules allows local thermal excitations to disrupt the crystalline order of a given chain piece-by-piece, giving it much poorer heat resistance than other high-strength fibers.
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