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K3PO4. Tripotassium phosphate has few industrial applications, however it is commonly used as a base in laboratory-scale organic chemistry. Being insoluble in organic solvents, it is an easily removed proton acceptor in organic synthesis. The anhydrous salt is especially basic. [5] Some of the reactions are listed below:
Monopotassium phosphate Dipotassium phosphate Tripotassium phosphate. Potassium phosphate is a generic term for the salts of potassium and phosphate ions including: [1] ...
Monopotassium phosphate can exist in several polymorphs.At room temperature it forms paraelectric crystals with tetragonal symmetry. Upon cooling to −150 °C (−238 °F) it transforms to a ferroelectric phase of orthorhombic symmetry, and the transition temperature shifts up to −50 °C (−58 °F) when hydrogen is replaced by deuterium. [8]
A general formula for such cyclic compounds is [HPO 3] x where x = number of phosphoric units in the molecule. When metaphosphoric acids lose their hydrogens as H +, cyclic anions called metaphosphates are formed. An example of a compound with such an anion is sodium hexametaphosphate (Na 6 P 6 O 18), used as a sequestrant and a food additive.
The following chart shows the solubility of various ionic compounds in water at 1 atm pressure and room temperature (approx. 25 °C, 298.15 K). "Soluble" means the ionic compound doesn't precipitate, while "slightly soluble" and "insoluble" mean that a solid will precipitate; "slightly soluble" compounds like calcium sulfate may require heat to precipitate.
The mechanism of the Michaelis–Arbuzov reaction. The Michaelis–Arbuzov reaction is initiated with the S N 2 attack of the nucleophilic phosphorus species (1 - A phosphite) with the electrophilic alkyl halide (2) to give a phosphonium salt as an intermediate (3).
Potassium phosphide is an inorganic semiconductor compound with the formula K 3 P. It appears as a white crystalline solid or powder. [2] It reacts violently with water and is toxic via ingestion, inhalation and skin absorption. [3] It has a hexagonal structure. [1]
behave as separate weak acids because the successive pK a differ by more than 4. Phosphate can form many polymeric ions such as pyrophosphate, (P 2 O 7) 4−, and triphosphate, (P 3 O 10) 5−. The various metaphosphate ions (which are usually long linear polymers) have an empirical formula of (PO 3) − and are found in many compounds.