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Magnesium oxide (Mg O), or magnesia, is a white hygroscopic solid mineral that occurs naturally as periclase and is a source of magnesium (see also oxide). It has an empirical formula of MgO and consists of a lattice of Mg 2+ ions and O 2− ions held together by ionic bonding .
The charge of the resulting ions is a major factor in the strength of ionic bonding, e.g. a salt C + A − is held together by electrostatic forces roughly four times weaker than C 2+ A 2− according to Coulomb's law, where C and A represent a generic cation and anion respectively. The sizes of the ions and the particular packing of the ...
In the ground state the binding energy or MgAr + is 1281 cm −1 and in the A 2 Π 1 / 2 state is 5554 cm −1 (3.66 kcal/mol). [1] The A 2 Π 1 / 2 state has a stronger bond because a p electron overlaps the argon atom less, and thus has less repulsion. [2] The dissociation energy of the ground state ion is 1295 cm −1 (15 kJ ...
Simple illustration of particles in the solid state – they are closely packed to each other. In a solid, constituent particles (ions, atoms, or molecules) are closely packed together. The forces between particles are so strong that the particles cannot move freely but can only vibrate. As a result, a solid has a stable, definite shape, and a ...
The particles are held very close to each other. Amorphous solid: A solid in which there is no far-range order of the positions of the atoms. Crystalline solid: A solid in which atoms, molecules, or ions are packed in regular order. Quasicrystal: A solid in which the positions of the atoms have long-range order, but this is not in a repeating ...
A large molecule with an ionized group is technically an ion, but its behavior may be largely the result of non-ionic interactions. For example, sodium stearate (the main constituent of traditional soaps) consists entirely of ions, yet it is a soft material quite unlike a typical ionic solid. There is a continuum between ionic solids and ...
Periclase is a magnesium mineral that occurs naturally in contact metamorphic rocks and is a major component of most basic refractory bricks. It is a cubic form of magnesium oxide (Mg O). In nature it usually forms a solid solution with wüstite (FeO) and is then referred to as ferropericlase or magnesiowüstite. [6]
In both, magnesium oxide is the precursor to magnesium metal. The magnesium oxide is produced as a solid solution with calcium oxide by calcining the mineral dolomite, which is a solid solution of calcium and magnesium carbonates: CaCO 3 ·MgCO 3 → MgO·CaO + 2 CO 2. Reduction occurs at high temperatures with silicon.