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According to both ab initio calculations and the experimental X-ray structure, the cation is planar, symmetric, and approximately V-shaped, with bond angles 111° at the central atom (angle N2–N3–N4) and 168° at the second and fourth atoms (angles N1–N2–N3 and N3–N4–N5). The bond lengths for N1–N2 and N4–N5 are 1.10 Å and the ...
The 15 N: 14 N ratio is commonly used in stable isotope analysis in the fields of geochemistry, hydrology, paleoclimatology and paleoceanography, where it is called δ 15 N. [40] Of the thirteen other isotopes produced synthetically, ranging from 9 N to 23 N, 13 N has a half-life of ten minutes and the remaining isotopes have half-lives less ...
In chemistry, azide (/ ˈ eɪ z aɪ d /, AY-zyd) is a linear, polyatomic anion with the formula N − 3 and structure − N=N + =N −. It is the conjugate base of hydrazoic acid HN 3. Organic azides are organic compounds with the formula RN 3, containing the azide functional group. [1] The dominant application of azides is as a propellant in ...
Many stoichiometric phases are usually present for most elements (e.g. MnN, Mn 6 N 5, Mn 3 N 2, Mn 2 N, Mn 4 N, and Mn x N for 9.2 < x < 25.3). They may be classified as "salt-like" (mostly ionic), covalent, "diamond-like", and metallic (or interstitial ), although this classification has limitations generally stemming from the continuity of ...
As a linear and symmetric molecule, it has D ∞h symmetry, with a nitrogen–nitrogen bond length averaging 1.8115 Å. The first excited electronic state, A 2 Σ u, is 4.56 eV above the ground state. [1] The cyclic form was identified in 2003 by N. Hansen and A. M. Wodtke using ultraviolet photolysis of chlorine azide. Although the reaction ...
The sum of oxidation states in the ion equals its charge (as it equals zero for a neutral molecule). Also in anions, the formal (ionic) charges have to be considered when nonzero. For sulfate this is exemplified with the skeletal or Lewis structures (top), compared with the bond-order formula of all oxygens equivalent and fulfilling the octet ...
In the NO − 3 anion, the oxidation state of the central nitrogen atom is V (+5). This corresponds to the highest possible oxidation number of nitrogen. Nitrate is a potentially powerful oxidizer as evidenced by its explosive behaviour at high temperature when it is detonated in ammonium nitrate (NH 4 NO 3), or black powder, ignited by the shock wave of a primary explosive.
S 4 N 4 is also unstable with respect to the elements, but less so that the isostructural Se 4 N 4. Heating S 4 N 4 gives a polymer, and a variety of molecular sulfur nitride anions and cations are also known. Related to but distinct from nitride is pernitride diatomic anion (N 2− 2) and the azide triatomic anion (N 3-).