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The electron Zeeman interaction describes the interaction between an electron spin and the applied magnetic field. The nuclear Zeeman interaction is the interaction of the magnetic moment of the proton with an applied magnetic field. The hyperfine interaction is the coupling between the electron spin and the proton's nuclear spin.
Bruker 700 MHz nuclear magnetic resonance (NMR) spectrometer. Nuclear Magnetic Resonance (NMR) basic principles. Nuclear magnetic resonance (NMR) is a physical phenomenon in which nuclei in a strong constant magnetic field are disturbed by a weak oscillating magnetic field (in the near field [1]) and respond by producing an electromagnetic signal with a frequency characteristic of the magnetic ...
Nuclear magnetic resonance (NMR) spectroscopy uses the intrinsic magnetic moment that arises from the spin angular momentum of a spin-active nucleus. [1] If the element of interest has a nuclear spin that is not 0, [1] the nucleus may exist in different spin angular momentum states, where the energy of these states can be affected by an external magnetic field.
The Rabi frequency should not be confused with the field's own frequency. Since many atomic nuclei species can behave as a magnetic dipole, this resonance technique is the basis of nuclear magnetic resonance, including nuclear magnetic resonance imaging and nuclear magnetic resonance spectroscopy.
Electron paramagnetic resonance (EPR) or electron spin resonance (ESR) spectroscopy is a method for studying materials that have unpaired electrons. The basic concepts of EPR are analogous to those of nuclear magnetic resonance (NMR), but the spins excited are those of the electrons instead of the atomic nuclei .
Mössbauer observed resonance in nuclei of solid iridium, which raised the question of why gamma-ray resonance was possible in solids but not in gases. Mössbauer proposed that, for the case of atoms bound into a solid, a fraction of the nuclear events could occur essentially without recoil under certain circumstances.
Nuclear quadrupole resonance spectroscopy or NQR is a chemical analysis technique related to nuclear magnetic resonance . Unlike NMR, NQR transitions of nuclei can be detected in the absence of a magnetic field , and for this reason NQR spectroscopy is referred to as " zero Field NMR ".
This difference reflects the large magnetic moment of an electron (−1.00 μB), which is much greater than any nuclear magnetic moment (e.g. for 1 H: 1.52×10 −3 μB). Owing to rapid spin relaxation, the electron-nuclear coupling is not observed in the NMR spectrum, so the affected nuclear resonance appears at the average of the two coupled ...