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Chlorofluorocarbons (CFCs), once major components of numerous commercial aerosol products, have proven damaging to Earth's ozone layer and resulted in the wide-reaching Montreal Protocol; though in truth the chlorine in CFCs is the destructive actor, fluorine is an important part of these molecules because it makes them very stable and long-lived.
Organofluorine compounds are prepared by numerous routes, depending on the degree and regiochemistry of fluorination sought and the nature of the precursors. The direct fluorination of hydrocarbons with F 2, often diluted with N 2, is useful for highly fluorinated compounds: R 3 CH + F 2 → R 3 CF + HF
The oxidation states are also maintained in articles of the elements (of course), and systematically in the table {{Infobox element/symbol-to-oxidation-state}} See also [ edit ]
Several elements show their highest oxidation state only in a few compounds, one of which is the fluoride; and some elements' highest known oxidation state is seen exclusively in a fluoride. For groups 1–5, 13–16 (except nitrogen), the highest oxidation states of oxides and fluorides are always equal. Differences are only seen in chromium ...
ClO 2 F was first reported by Schmitz and Schumacher in 1942, who prepared it by the fluorination of ClO 2. [2] The compound is more conveniently prepared by reaction of sodium chlorate and chlorine trifluoride [3] and purified by vacuum fractionation, i.e. selectively condensing this species separately from other products. This species is a ...
In compounds, fluorine almost exclusively assumes an oxidation state of −1. Fluorine in F 2 is defined to have oxidation state 0. The unstable species F − 2 and F − 3, which decompose at around 40 K, have intermediate oxidation states; [100] F + 4 and a few related species are predicted to be stable. [101]
The lethal dose for most adult humans is estimated at 5 to 10 g (which is equivalent to 32 to 64 mg elemental fluoride per kg body weight). [ 53 ] [ 54 ] [ 55 ] A case of a fatal poisoning of an adult with 4 grams of sodium fluoride is documented, [ 56 ] and a dose of 120 g sodium fluoride has been survived. [ 57 ]
Chlorine and oxygen can bond in a number of ways: chlorine monoxide radical, ClO•, chlorine (II) oxide radical; chloroperoxyl radical, ClOO•, chlorine (II) peroxide radical; chlorine dioxide, ClO 2, chlorine (IV) oxide; chlorine trioxide radical, ClO 3 •, chlorine (VI) oxide radical; chlorine tetroxide radical, ClO 4 •, chlorine (VII ...