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Heyrovský's Polarograph. Polarography is an electrochemical voltammetric technique that employs (dropping or static) mercury drop as a working electrode. In its most simple form polarography can be used to determine concentrations of electroactive species in liquids by measuring their mass-transport limiting currents.
In diving service a cell typically lasts for 12 to 18 months, with perhaps 150 hours service in the diving loop at an oxygen partial pressure of about 1.2 bar and the rest of the time in storage in air at room temperature. [1] Failures in cells can be life-threatening for technical divers and in particular, rebreather divers. [8]
Voltammetry is the study of current as a function of applied potential. Voltammetric methods involve electrochemical cells, and investigate the reactions occurring at electrode/electrolyte interfaces. [4]
Galvanic corrosion is the electrochemical erosion of metals. Corrosion occurs when two dissimilar metals are in contact with each other in the presence of an electrolyte, such as salt water. This forms a galvanic cell, with hydrogen gas forming on the more noble (less active) metal.
An oxygen sensor (or lambda sensor, where lambda refers to air–fuel equivalence ratio, usually denoted by λ) or probe or sond, is an electronic device that measures the proportion of oxygen (O 2) in the gas or liquid being analyzed. [1] It was developed by Robert Bosch GmbH during the late 1960s under the supervision of Günter Bauman. [1]
Sensors are usually designed so that the gas supply is limited by diffusion, and thus the output from the sensor is linearly proportional to the gas concentration. This linear output is one of the advantages of electrochemical sensors over other sensor technologies (e.g. infrared), whose output must be linearized before they can be used.
Galvanism: electrodes touch a frog, and the legs twitch into the upward position [1]. Galvanism is a term invented by the late 18th-century physicist and chemist Alessandro Volta to refer to the generation of electric current by chemical action. [2]
Most electrodes work over a limited range of conditions, such as pH or temperature, outside of this range the electrodes behavior becomes unpredictable. The advantage of a pseudo-reference electrode is that the resulting variation is factored into the system allowing researchers to accurately study systems over a wide range of conditions.