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Recrystallization is a method used to purify chemicals by dissolving a mixture of a compound and its impurities, in an appropriate solvent, prior to heating the solution. [1] Following the dissolution of crude product, the mixture will passively cool, yielding a crystallized compound and its impurities as separate entities.
Recrystallization may occur during or after deformation (during cooling or subsequent heat treatment, for example). The former is termed dynamic while the latter is termed static . In addition, recrystallization may occur in a discontinuous manner, where distinct new grains form and grow, or a continuous manner, where the microstructure ...
In this example, assuming a racemate (50:50 mix of enantiomers), then with a eutectic of 0.23, the maximum yield we can expect from system, via crystallization, is 35%. Diastereomeric recrystallisation is a method of chiral resolution of enantiomers from a racemic mixture.
In metallurgy, materials science and structural geology, subgrain rotation recrystallization is recognized as an important mechanism for dynamic recrystallisation.It involves the rotation of initially low-angle sub-grain boundaries until the mismatch between the crystal lattices across the boundary is sufficient for them to be regarded as grain boundaries.
Recrystallization to coarser crystals lowers the Gibbs free energy by reducing surface energy, [18] while phase changes and neocrystallization reduce the bulk Gibbs free energy. A reaction will begin at the temperature and pressure where the Gibbs free energy of the reagents becomes greater than that of the products.
Recovery competes with recrystallization, as both are driven by the stored energy, but is also thought to be a necessary prerequisite for the nucleation of recrystallized grains. It is so called because there is a recovery of the electrical conductivity due to a reduction in dislocations.
TsOH is most often supplied as the monohydrate, and it may be necessary to remove the complexed water before use. Impurities can be removed by recrystallization from its concentrated aqueous solution followed by azeotropic drying with toluene. [2] TsOH finds use in organic synthesis as an "organic-soluble" strong acid. Examples of uses include:
Dynamic quartz recrystallization happens in a relatively predictable way with relation to temperature, and given its abundance quartz recrystallization can be used to easily determine relative temperature profiles, for example in orogenic belts or near intrusions.