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  2. Mechanical equilibrium - Wikipedia

    en.wikipedia.org/wiki/Mechanical_equilibrium

    A stationary object (or set of objects) is in "static equilibrium," which is a special case of mechanical equilibrium. A paperweight on a desk is an example of static equilibrium. Other examples include a rock balance sculpture, or a stack of blocks in the game of Jenga , so long as the sculpture or stack of blocks is not in the state of ...

  3. Gibbs free energy - Wikipedia

    en.wikipedia.org/wiki/Gibbs_free_energy

    The maximum work is thus regarded as the diminution of the free, or available, energy of the system (Gibbs free energy G at T = constant, P = constant or Helmholtz free energy F at T = constant, V = constant), whilst the heat given out is usually a measure of the diminution of the total energy of the system (internal energy).

  4. Maxwell construction - Wikipedia

    en.wikipedia.org/wiki/Maxwell_construction

    The discontinuity in , and other properties, e.g. internal energy, , and entropy,, of the substance, is called a first order phase transition. [12] [13] In order to specify the unique experimentally observed pressure, (), at which it occurs another thermodynamic condition is required, for from Fig.1 it could clearly occur for any pressure in the range .

  5. Lami's theorem - Wikipedia

    en.wikipedia.org/wiki/Lami's_theorem

    In physics, Lami's theorem is an equation relating the magnitudes of three coplanar, concurrent and non-collinear vectors, which keeps an object in static equilibrium, with the angles directly opposite to the corresponding vectors.

  6. Thermodynamic state - Wikipedia

    en.wikipedia.org/wiki/Thermodynamic_state

    Mechanical equilibrium: If at every point within a given system there is no change in pressure with time, and there is no movement of material, the system is in mechanical equilibrium. Phase equilibrium : This occurs when the mass for each individual phase reaches a value that does not change with time.

  7. Statics - Wikipedia

    en.wikipedia.org/wiki/Statics

    The static equilibrium of a particle is an important concept in statics. A particle is in equilibrium only if the resultant of all forces acting on the particle is equal to zero. In a rectangular coordinate system the equilibrium equations can be represented by three scalar equations, where the sums of forces in all three directions are equal ...

  8. Newton's laws of motion - Wikipedia

    en.wikipedia.org/wiki/Newton's_laws_of_motion

    A state of mechanical equilibrium is stable if, when the position of the body is changed slightly, the body remains near that equilibrium. Otherwise, the equilibrium is unstable. A common visual representation of forces acting in concert is the free body diagram , which schematically portrays a body of interest and the forces applied to it by ...

  9. Free-energy relationship - Wikipedia

    en.wikipedia.org/wiki/Free-energy_relationship

    The Hammett equation predicts the equilibrium constant or reaction rate of a reaction from a substituent constant and a reaction type constant. The Edwards equation relates the nucleophilic power to polarisability and basicity. The Marcus equation is an example of a quadratic free-energy relationship (QFER). [citation needed]