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Flash vacuum pyrolysis (FVP) is a technique in organic synthesis. It entails heating a precursor molecule intensely and briefly. It entails heating a precursor molecule intensely and briefly. Two key parameters are the temperature and duration (or residence time), which are adjusted to optimize yield, conversion, and avoidance of intractable ...
Thermal rearrangements of aromatic hydrocarbons are generally carried out through flash vacuum pyrolysis (FVP). [14] In a typical FVP apparatus, a sample is sublimed under high vacuum (0.1-1.0 mmHg ), heated in the range of 500-1100 °C by an electric furnace as it passes through a horizontal quartz tube, and collected in a cold trap.
Vacuum Ovens use pyrolysis in a vacuum [92] avoiding uncontrolled combustion inside the cleaning chamber; [87] the cleaning process takes 8 [88] to 30 hours. [93] Burn-Off Ovens, also known as Heat-Cleaning Ovens, are gas-fired and used in the painting, coatings, electric motors and plastics industries for removing organics from heavy and large ...
The first demonstration of reactive flash volatilization occurred by a series of experimental steps: [7] The researchers start with either pure soybean oil or a thick sugar syrup. The reactor consists of an automotive fuel injector, used to spray the oil or syrup as fine droplets through a tube.
Pyrolysis is the thermal decomposition of materials in an inert atmosphere or a vacuum. The sample is put into direct contact with a platinum wire, or placed in a quartz sample tube, and rapidly heated to 600–1000 °C. Depending on the application even higher temperatures are used.
Scheme for dehalogenation reaction (R = alkyl or aryl group, X = I, Cl, Br, F) In organic chemistry, dehalogenation is a set of chemical reactions that involve the cleavage of carbon-halogen bonds; as such, it is the inverse reaction of halogenation.
Flash vacuum pyrolysis techniques generally have lower chemical yields than solution-chemistry syntheses, but offer routes to more derivatives. Corannulene was first isolated in 1966 by multistep organic synthesis. [4] In 1971, the synthesis and properties of corannulane were reported. [5] A flash vacuum pyrolysis method followed in 1991. [6]
Pyrolysis of anhydrides and intramolecular hydrogen transfer in a propiolic acid can also make alkylidene ketenes. This particular transformation is believed to go through a propiolaldehyde intermediate that generates acetylene via carbon monoxide loss. [13] Methylene ketene from flash vacuum pyrolysis of acrylic anhydride [13]