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The optical spectrum of this d 6 octahedral complex exhibits an intense absorption near 250 nm corresponding to a transition from ligand σ MO to the empty e g MO. In IrBr 6 2−, which is a d 5 complex, two absorptions, one near 600 nm and another near 270 nm, are observed. These are assigned as two LMCT bands, one to t 2g and another to e g.
In chemistry, charge-transfer (CT) complex, or electron donor-acceptor complex, describes a type of supramolecular assembly of two or more molecules or ions. The assembly consists of two molecules that self-attract through electrostatic forces, i.e., one has at least partial negative charge and the partner has partial positive charge, referred ...
For example, d-wave or triplet superconductor, or a Fulde–Ferrell–Larkin–Ovchinnikov superconductor. Ferromagnetic superconductor: Materials that display intrinsic coexistence of ferromagnetism and superconductivity. Charge-4e superconductor: A proposed state in which electrons are not bound as Cooper pairs but as quadruplets of electrons.
For ML a 4 L b 2, two isomers exist.These isomers of ML a 4 L b 2 are cis, if the L b ligands are mutually adjacent, and trans, if the L b groups are situated 180° to each other. It was the analysis of such complexes that led Alfred Werner to the 1913 Nobel Prize–winning postulation of octahedral complexes.
Chemical classification systems attempt to classify elements or compounds according to certain chemical functional or structural properties. Whereas the structural properties are largely intrinsic, functional properties and the derived classifications depend to a certain degree on the type of chemical interaction partners on which the function is exerted.
For example, the absorption spectrum for ethane shows a σ → σ* transition at 135 nm and that of water a n → σ* transition at 167 nm with an extinction coefficient of 7,000. Benzene has three aromatic π → π* transitions; two E-bands at 180 and 200 nm and one B-band at 255 nm with extinction coefficients respectively 60,000, 8,000 and 215.
In chemistry, racemization is a conversion, by heat or by chemical reaction, of an optically active compound into a racemic (optically inactive) form. This creates a 1:1 molar ratio of enantiomers and is referred to as a racemic mixture (i.e. contain equal amount of (+) and (−) forms).
Magnus's green salt is an example of a linear chain compound. In chemistry and materials science, linear chain compounds are materials composed of one-dimensional arrays of metal-metal bonded molecules or ions. Such materials exhibit anisotropic electrical conductivity. [1] [2]
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