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Many phosphates are soluble in water at standard temperature and pressure. The sodium, potassium, rubidium, caesium, and ammonium phosphates are all water-soluble. Most other phosphates are only slightly soluble or are insoluble in water. As a rule, the hydrogen and dihydrogen phosphates are slightly more soluble than the corresponding phosphates.
Phosphorus can encourage excessive growths of plants and algae and contribute to eutrophication. If a river discharges into a lake or reservoir phosphate can be mobilised year after year by natural processes. In the summer time, lakes stratify so that warm oxygen rich water floats on top of cold oxygen poor water.
The hydrophilic end usually contains a negatively charged phosphate group, and the hydrophobic end usually consists of two "tails" that are long fatty acid residues. [ 4 ] In aqueous solutions, phospholipids are driven by hydrophobic interactions , which result in the fatty acid tails aggregating to minimize interactions with the water molecules.
In aqueous solutions (solutions of water), water gradually (over the course of hours) hydrolyzes polyphosphates into smaller phosphates and finally into ortho-phosphate, given enough water. Higher temperature or acidic conditions can speed up the hydrolysis reactions considerably.
Boiler water is treated to prevent scaling, corrosion, foaming, and priming. Chemicals are put into boiler water through the chemical feed tank to keep the water within chemical range. These chemicals are mostly oxygen scavengers and phosphates. The boiler water also has frequent blowdowns in order to keep the chloride content down.
Elemental phosphorus was first isolated from human urine, and bone ash was an important early phosphate source. Phosphate mines contain fossils because phosphate is present in the fossilized deposits of animal remains and excreta. Low phosphate levels are an important limit to growth in a number of plant ecosystems.
Phosphates have low toxicity in the environment but cause nutrient pollution, a major water quality problem in many watersheds. [17] Phosphates in water cause eutrophication of algae which creates conditions favorable to formation of harmful algal blooms. These blooms prevent light and oxygen from getting into the water, leading to the death of ...
Maintaining optimal pH is important for the removal of phosphorus from water. Phosphorus is most effectively removed at the neutral pH range, when the insoluble aluminum hydroxide is present. This hydroxide functions as a Lewis acid, [5] creating a flocculation environment similar to conventional wastewater treatment.