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The oxidation of primary alcohols to carboxylic acids can be carried out using a variety of reagents, but O 2 /air and nitric acid dominate as the oxidants on a commercial scale. Large scale oxidations of this type are used for the conversion of cyclohexanol alone or as a mixture with cyclohexanone to adipic acid. Similarly cyclododecanol is ...
Phenylacetic acid (conjugate base phenylacetate), also known by various synonyms, is an organic compound containing a phenyl functional group and a carboxylic acid functional group. It is a white solid with a strong honey-like odor .
Benzyl alcohol is a colorless liquid with a mild pleasant aromatic odor. It is useful as a solvent for its polarity, low toxicity, and low vapor pressure. Benzyl alcohol has moderate solubility in water (4 g/100 mL) and is miscible in alcohols and diethyl ether.
This page contains tables of azeotrope data for various binary and ternary mixtures of solvents. The data include the composition of a mixture by weight (in binary azeotropes, when only one fraction is given, it is the fraction of the second component), the boiling point (b.p.) of a component, the boiling point of a mixture, and the specific gravity of the mixture.
The benzilic acid rearrangement is formally the 1,2-rearrangement of 1,2-diketones to form α-hydroxy–carboxylic acids using a base. This reaction receives its name from the reaction of benzil with potassium hydroxide to form benzilic acid. First performed by Justus von Liebig in 1838, [1] it is the first reported example of a rearrangement ...
In general, for an acid AH n at concentration c 1 reacting with a base B(OH) m at concentration c 2 the volumes are related by: n v 1 c 1 = m v 2 c 2. An example of a base being neutralized by an acid is as follows. Ba(OH) 2 + 2 H + → Ba 2+ + 2 H 2 O. The same equation relating the concentrations of acid and base applies.
This can be economically viable if the products can be separated and both have a value; the commercial conversion of furfural into furfuryl alcohol and 2-furoic acid is an example of this. [6] Alternatively, higher yields of one product (usually the alcohol) can be achieved in the crossed Cannizzaro reaction , in which a sacrificial aldehyde is ...
Phenethyl alcohol, or 2-phenylethanol, is an organic compound with the chemical formula C 6 H 5 CH 2 CH 2 OH.It is a colourless liquid with a pleasant floral odor. It occurs widely in nature, being found in a variety of essential oils.