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Two radiometric dating methods involve thorium isotopes: uranium–thorium dating, based on the decay of 234 U to 230 Th, and ionium–thorium dating, which measures the ratio of 232 Th to 230 Th. [e] These rely on the fact that 232 Th is a primordial radioisotope, but 230 Th only occurs as an intermediate decay product in the decay chain of ...