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The N–N single bond length is 1.447(2) Å (144.7(2) pm), the N-H distance is 1.015(2) Å, the N-N-H angles are 106(2)° and 112(2)°, the H-N-H angle is 107°. [49] The molecule adopts a gauche conformation with a torsion angle of 91(2)° (dihedral angle between the planes containing the N-N bond and the bisectors of the H-N-H angles).
Methylene imine is an organic compound with the chemical formula H 2 C=NH. The simplest imine , it is a stable, colorless gas that has been detected throughout the universe. [ 1 ] Structural parameters determined by microwave spectroscopy include a C=N bond length of 1.27 Å , an N–H bond length of 1.02 Å and an H−N=C bond angle of 110.5 ...
The surface energy of a solid is the free energy per unit area of its surface. It equals half the energy per unit area needed for cutting a larger piece of solid in two parts along the surface under examination. This costs energy because chemical bonds are broken. [1] Typically, materials are considered to have one specific surface energy.
Using the electroneutrality principle the assumption is made that the Co-N bond will have 50% ionic character thus resulting in a zero charge on the cobalt atom. Due to the difference in electronegativity the N-H bond would 17% ionic character and therefore a charge of 0.166 on each of the 18 hydrogen atoms.
The general notation for hydrogen bonding is Dn−H···Ac, where the solid line represents a polar covalent bond, and the dotted or dashed line indicates the hydrogen bond. [6] The most frequent donor and acceptor atoms are nitrogen (N), oxygen (O), and fluorine (F), due to their high electronegativity and ability to engage in stronger ...
A solid with extensive hydrogen bonding will be considered a molecular solid, yet strong hydrogen bonds can have a significant degree of covalent character. As noted above, covalent and ionic bonds form a continuum between shared and transferred electrons; covalent and weak bonds form a continuum between shared and unshared electrons.
The product is light-sensitive and can undergo disproportionation to lithium amide and characteristically red lithium nitride. 2 Li 2 NH → LiNH 2 + Li 3 N Lithium imide is thought to have a simple face-centered cubic structure with a Fm 3 m space group ; with N-H bond distances of 0.82(6) Å and a H–N–H bond angle of 109.5°, giving it a ...
A molecular solid is a solid consisting of discrete molecules. The cohesive forces that bind the molecules together are van der Waals forces , dipole–dipole interactions , quadrupole interactions , π–π interactions , hydrogen bonding , halogen bonding , London dispersion forces , and in some molecular solids, coulombic interactions .