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A representation of Hess's law (where H represents enthalpy) Hess's law of constant heat summation, also known simply as Hess's law, is a relationship in physical chemistry and thermodynamics [1] named after Germain Hess, a Swiss-born Russian chemist and physician who published it in 1840.
The caloric theory is an obsolete scientific theory that heat consists of a self-repellent fluid called caloric that flows from hotter bodies to colder bodies. Caloric was also thought of as a weightless gas that could pass in and out of pores in solids and liquids.
The flow of heat is a form of energy transfer. Heat transfer is the natural process of moving energy to or from a system, other than by work or the transfer of matter. In a diathermal system, the internal energy can only be changed by the transfer of energy as heat: =.
But before the redefinition, the triple point of water was exact and the Boltzmann constant had a measured value of 1.380 649 03 (51) × 10 −23 J/K, with a relative standard uncertainty of 3.7 × 10 −7. [51] Afterward, the Boltzmann constant is exact and the uncertainty is transferred to the triple point of water, which is now 273.1600(1) K ...
Calorimetry requires that a reference material that changes temperature have known definite thermal constitutive properties. The classical rule, recognized by Clausius and Kelvin, is that the pressure exerted by the calorimetric material is fully and rapidly determined solely by its temperature and volume; this rule is for changes that do not involve phase change, such as melting of ice.
Heat transfer is a discipline of thermal engineering that concerns the generation, use, conversion, and exchange of thermal energy between physical systems. Heat transfer is classified into various mechanisms, such as thermal conduction, thermal convection, thermal radiation, and transfer of energy by phase changes.
Thermal physics, generally speaking, is the study of the statistical nature of physical systems from an energetic perspective. Starting with the basics of heat and temperature, thermal physics analyzes the first law of thermodynamics and second law of thermodynamics from the statistical perspective, in terms of the number of microstates corresponding to a given macrostate.
The heat capacity of an object, denoted by , is the limit =, where is the amount of heat that must be added to the object (of mass M) in order to raise its temperature by . The value of this parameter usually varies considerably depending on the starting temperature T {\displaystyle T} of the object and the pressure p {\displaystyle p} applied ...
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