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The Debye–Hückel theory was proposed by Peter Debye and Erich Hückel as a theoretical explanation for departures from ideality in solutions of electrolytes and plasmas. [1] It is a linearized Poisson–Boltzmann model , which assumes an extremely simplified model of electrolyte solution but nevertheless gave accurate predictions of mean ...
Scripps Research is a nonprofit American medical research facility that focuses on research and education in the biomedical sciences.Headquartered in San Diego, California, the institute has over 170 laboratories employing 2,100 scientists, [1] technicians, graduate students, and administrative and other staff.
Substituting this length scale into the Debye–Hückel equation and neglecting the second and third terms on the right side yields the much simplified form () = ().As the only characteristic length scale in the Debye–Hückel equation, sets the scale for variations in the potential and in the concentrations of charged species.
Lars Onsager was born in Kristiania (now Oslo), Norway.His father was a lawyer.After completing secondary school in Oslo, he attended the Norwegian Institute of Technology (NTH) in Trondheim, graduating as a chemical engineer in 1925.
It is based on the classic theory of polar liquids, as developed by Peter Debye and corrected by Lars Onsager to incorporate reaction field effects. The model can be combined with quantum chemical calculations to formally derive a continuum model of solvent effects suitable for computer simulations of small and large molecular systems.
He is mainly known for the Debye–Hückel theory of electrolytic solutions and the Hückel method of approximate molecular orbital (MO) calculations on π electron systems. Hückel was born in the Charlottenburg suburb of Berlin. He studied physics and mathematics from 1914 to 1921 at the University of Göttingen.
The Lars Onsager Prize is a prize in theoretical statistical physics awarded annually by the American Physical Society. Prize recipients receive a medal, certificate, and $10,000. [ 1 ] It was established in 1993 by Drs. Russell and Marian Donnelly [ 2 ] in memory of Lars Onsager .
An explanation of the Debye-Hueckel/Kirkwood charging process is missing, and that section of the derivation (the evaluation of integration constants) could be done more clearly, with a particular focus on the activity coefficient. Also, the Debye-Hueckel model does not conform to a Helmholtz model of the double-layer, rather a Gouy-Chapman model.
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