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Catalytic oxidation with oxygen or air is a major application of green chemistry. There are however many oxidations that cannot be achieved so straightforwardly. The conversion of propylene to propylene oxide is typically effected using hydrogen peroxide, not oxygen or air.
Some of the largest-scale chemicals are produced via catalytic oxidation, often using oxygen. Examples include nitric acid (from ammonia), sulfuric acid (from sulfur dioxide to sulfur trioxide by the contact process ), terephthalic acid from p-xylene, acrylic acid from propylene or propane and acrylonitrile from propane and ammonia.
Oxidation of hydrocarbons (unburnt and partially burned fuel) to carbon dioxide and water: C x H 2x+2 + [(3x+1)/2]O 2 → xCO 2 + (x+1)H 2 O (a combustion reaction) The two-way catalytic converter is widely used on diesel engines to reduce hydrocarbon and carbon monoxide emissions. They were also used on gasoline engines in American and ...
Catalytic oxidizer (also known as catalytic incinerator) is another category of oxidation systems that is similar to typical thermal oxidizers, but the catalytic oxidizers use a catalyst to promote the oxidation. Catalytic oxidation occurs through a chemical reaction between the VOC hydrocarbon molecules and a precious-metal catalyst bed that ...
Catalytic combustion is a chemical process which uses a catalyst to speed desired oxidation reactions of fuel and so reduce the formation of undesired products, especially pollutant nitrogen oxide gases (NO x) far below what can be achieved without catalysts. The process was discovered in the 1950s by Catalytic Combustion LLC.
Hydrogenation of ethene on a catalytic solid surface (1) Adsorption (2) Reaction (3) Desorption. Heterogeneous catalysis is catalysis where the phase of catalysts differs from that of the reagents or products. [1] The process contrasts with homogeneous catalysis where the reagents, products and catalyst exist in the same phase.
A catalytic converter is a metal cylinder or flattened oval that’s part of the car’s exhaust system. It’s usually underneath the car with an exhaust pipe running in one end and out the other.
The oxidation of hydrocarbons by air or oxygen is the basis of autoxidation. Like many radical reactions, the rate vs time plot shows a sigmoidal behavior, characteristic of autocatalysis. [ 5 ] Many reactions of organic compounds with halogen involve autocatalytic radical mechanisms .