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The kinetic theory of gases is a simple classical model of the thermodynamic behavior of gases. It treats a gas as composed of numerous particles, too small to see with a microscope, which are constantly in random motion.
Brownian motion. Simulation of the Brownian motion of a large particle, analogous to a dust particle, that collides with a large set of smaller particles, analogous to molecules of a gas, which move with different velocities in different random directions. Brownian motion is the random motion of particles suspended in a medium (a liquid or a gas).
In physics (specifically, the kinetic theory of gases), the Einstein relation is a previously unexpected [clarification needed] connection revealed independently by William Sutherland in 1904, [ 1 ][ 2 ][ 3 ] Albert Einstein in 1905, [ 4 ] and by Marian Smoluchowski in 1906 [ 5 ] in their works on Brownian motion.
The van der Waals equation, named for its originator, the Dutch physicist Johannes Diderik van der Waals, is an equation of state that extends the ideal gas law to include the non-zero size of gas molecules and the interactions between them (both of which depend on the specific substance). As a result the equation is able to model the liquid ...
μ is the mobility of the particle in the fluid or gas, which can be calculated using the Einstein relation (kinetic theory). m is the mass of the particle. t is time. At long time scales, Einstein's result is recovered, but short time scales, the ballistic regime are also explained.
A particle speed probability distribution indicates which speeds are more likely: a randomly chosen particle will have a speed selected randomly from the distribution, and is more likely to be within one range of speeds than another. The kinetic theory of gases applies to the classical ideal gas, which is an
The general equation can then be written as [6] = + + (),. where the "force" term corresponds to the forces exerted on the particles by an external influence (not by the particles themselves), the "diff" term represents the diffusion of particles, and "coll" is the collision term – accounting for the forces acting between particles in collisions.
History of molecular theory. Space-filling model of the H 2 O molecule. In chemistry, the history of molecular theory traces the origins of the concept or idea of the existence of strong chemical bonds between two or more atoms. A modern conceptualization of molecules began to develop in the 19th century along with experimental evidence for ...