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Pure fluorite is colourless and transparent, both in visible and ultraviolet light, but impurities usually make it a colorful mineral and the stone has ornamental and lapidary uses. Industrially, fluorite is used as a flux for smelting, and in the production of certain glasses and enamels.
The fluorite structure refers to a common motif for compounds with the formula MX 2. [1] [2] The X ions occupy the eight tetrahedral interstitial sites whereas M ions occupy the regular sites of a face-centered cubic (FCC) structure. Many compounds, notably the common mineral fluorite (CaF 2), adopt this structure.
The main uses of fluoride, in terms of volume, are in the production of cryolite, Na 3 AlF 6. It is used in aluminium smelting. Formerly, it was mined, but now it is derived from hydrogen fluoride. Fluorite is used on a large scale to separate slag in steel-making. Mined fluorite (CaF 2) is a commodity chemical used in steel-making.
Its use began in the 1940s, following studies of children in a region where water is naturally fluoridated. It is now used widely in public water systems in the United States and some other parts of the world, such that about two-thirds of the U.S. population is exposed to fluoridated water supplies [5] and about 5.7% of people worldwide. [6]
Fluorite, the primary mineral source of fluorine, which gave the element its name, was first described in 1529; as it was added to metal ores to lower their melting points for smelting, the Latin verb fluo meaning ' to flow ' gave the mineral its name. Proposed as an element in 1810, fluorine proved difficult and dangerous to separate from its ...
Blue John (also known as Derbyshire Spar) is a semi-precious mineral, a rare form of fluorite with bands of a purple-blue or yellowish colour. In the United Kingdom it is found only at Blue John Cavern and Treak Cliff Cavern at Castleton in Derbyshire .
Fluorite of the acidspar grade is used directly as an additive to ceramics and enamels, glass fibers and clouded glass, and cement, as well as in the outer coating of welding rods. [5] Acidspar is primarily used for making hydrofluoric acid, which is a chemical intermediate for most fluorine-containing compounds.
Hydrogen fluoride is typically produced by the reaction between sulfuric acid and pure grades of the mineral fluorite: [14] CaF 2 + H 2 SO 4 → 2 HF + CaSO 4. About 20% of manufactured HF is a byproduct of fertilizer production, which generates hexafluorosilicic acid. This acid can be degraded to release HF thermally and by hydrolysis: H 2 SiF ...