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In chemistry, an acid–base reaction is a chemical reaction that occurs between an acid and a base.It can be used to determine pH via titration.Several theoretical frameworks provide alternative conceptions of the reaction mechanisms and their application in solving related problems; these are called the acid–base theories, for example, Brønsted–Lowry acid–base theory.
A Lewis base is also a Brønsted–Lowry base, but a Lewis acid does not need to be a Brønsted–Lowry acid. The classification into hard and soft acids and bases ( HSAB theory ) followed in 1963. The strength of Lewis acid-base interactions, as measured by the standard enthalpy of formation of an adduct can be predicted by the Drago–Wayland ...
A strong base is a basic chemical compound that can remove a proton (H +) from (or deprotonate) a molecule of even a very weak acid (such as water) in an acid–base reaction. Common examples of strong bases include hydroxides of alkali metals and alkaline earth metals, like NaOH and Ca(OH)
The E and C parameters refer, respectively, to the electrostatic and covalent contributions to the strength of the bonds that the acid and base will form. The equation is -ΔH = E A E B + C A C B + W. The W term represents a constant energy contribution for acid–base reaction such as the cleavage of a dimeric acid or base. The equation ...
A weak acid or the conjugate acid of a weak base can be treated using the same formalism. Acid HA: HA ⇌ H + + A −; Base A: HA + ⇌ H + + A; First, an acid dissociation constant is defined as follows. Electrical charges are omitted from subsequent equations for the sake of generality
The most common organic acids are the carboxylic acids, whose acidity is associated with their carboxyl group –COOH. Sulfonic acids, containing the group –SO 2 OH, are relatively stronger acids. Alcohols, with –OH, can act as acids but they are usually very weak. The relative stability of the conjugate base of
Another possibility is the molecular autoionization reaction between two water molecules, in which one water molecule acts as an acid and another as a base. H 2 O + H 2 O ⇌ H 3 O + + HO −. The bicarbonate ion, HCO − 3, is amphoteric as it can act as either an acid or a base: As an acid, losing a proton: HCO − 3 + OH − ⇌ CO 2− 3 ...
With pOH obtained from the pOH formula given above, the pH of the base can then be calculated from =, where pK w = 14.00. A weak base persists in chemical equilibrium in much the same way as a weak acid does, with a base dissociation constant (K b) indicating the strength of the base. For example, when ammonia is put in water, the following ...