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This energy, which can sometimes be harnessed (a simple example is a concentration cell), and the free-energy per mole is exactly equal to the electrochemical potential difference between the two regions.
A spontaneous electrochemical reaction (change in Gibbs free energy less than zero) can be used to generate an electric current in electrochemical cells. This is the basis of all batteries and fuel cells .
Electrochemical energy is one of the many interchangeable forms of potential energy through which energy may be conserved. It appears in electroanalytical chemistry and has industrial applications such as batteries and fuel cells. In biology, electrochemical gradients allow cells to control the direction ions move across membranes.
In a p–n junction diode at equilibrium the chemical potential (internal chemical potential) varies from the p-type to the n-type side, while the total chemical potential (electrochemical potential, or, Fermi level) is constant throughout the diode. As described above, when describing chemical potential, one has to say "relative to what".
Electric potential (also called the electric field potential, potential drop, the electrostatic potential) is defined as the amount of work/energy needed per unit of electric charge to move the charge from a reference point to a specific point in an electric field.
Bipolar electrochemistry scheme. In electrochemistry, standard electrode potential, or , is a measure of the reducing power of any element or compound.The IUPAC "Gold Book" defines it as; "the value of the standard emf (electromotive force) of a cell in which molecular hydrogen under standard pressure is oxidized to solvated protons at the left-hand electrode".
The electrochemical window (EW) of a substance is the electrode electric potential range between which the substance is neither oxidized nor reduced. The EW is one of the most important characteristics to be identified for solvents and electrolytes used in electrochemical applications. The EW is a term that is commonly used to indicate the ...
Potential energy is the energy by virtue of an object's position relative to other objects. [6] Potential energy is often associated with restoring forces such as a spring or the force of gravity. The action of stretching a spring or lifting a mass is performed by an external force that works against the force field of the potential.