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Conductivity (electrolytic) Conductivity or specific conductance of an electrolyte solution is a measure of its ability to conduct electricity. The SI unit of conductivity is siemens per meter (S/m). Conductivity measurements are used routinely in many industrial and environmental applications as a fast, inexpensive and reliable way of ...
The molar conductivity of an electrolyte solution is defined as its conductivity divided by its molar concentration. [1][2] where: κ is the measured conductivity (formerly known as specific conductance), [3] c is the molar concentration of the electrolyte. The SI unit of molar conductivity is siemens metres squared per mole (S m 2 mol −1). [2]
The SI unit of electrical resistivity is the ohm - metre (Ω⋅m). [1][2][3] For example, if a 1 m3 solid cube of material has sheet contacts on two opposite faces, and the resistance between these contacts is 1 Ω, then the resistivity of the material is 1 Ω⋅m. Electrical conductivity (or specific conductance) is the reciprocal of ...
This relationship is quantified by resistivity or conductivity. The nature of a material is not the only factor in resistance and conductance, however; it also depends on the size and shape of an object because these properties are extensive rather than intensive. For example, a wire's resistance is higher if it is long and thin, and lower if ...
The Debye–Hückel theory was proposed by Peter Debye and Erich Hückel as a theoretical explanation for departures from ideality in solutions of electrolytes and plasmas. [1] It is a linearized Poisson–Boltzmann model, which assumes an extremely simplified model of electrolyte solution but nevertheless gave accurate predictions of mean activity coefficients for ions in dilute solution.
Wilhelm Ostwald ’s dilution law is a relationship proposed in 1888 [1] between the dissociation constant Kd and the degree of dissociation α of a weak electrolyte. The law takes the form [2] Where the square brackets denote concentration, and c0 is the total concentration of electrolyte. Using , where is the molar conductivity at ...
In physics and electrical engineering, a conductor is an object or type of material that allows the flow of charge (electric current) in one or more directions. Materials made of metal are common electrical conductors. The flow of negatively charged electrons generates electric current, positively charged holes, and positive or negative ions in ...
Similar to electron conduction, the electrical resistance of thin-film electrolytes depends on the applied electric field, such that when the thickness of the sample is reduced, the conductivity improves due to both the reduced thickness and the field-induced conductivity enhancement.