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Conductivity (electrolytic) Conductivity or specific conductance of an electrolyte solution is a measure of its ability to conduct electricity. The SI unit of conductivity is siemens per meter (S/m). Conductivity measurements are used routinely in many industrial and environmental applications as a fast, inexpensive and reliable way of ...
For strong electrolytes, such as salts, strong acids and strong bases, the molar conductivity depends only weakly on concentration. On dilution there is a regular increase in the molar conductivity of strong electrolyte, due to the decrease in solute–solute interaction. Based on experimental data Friedrich Kohlrausch (around the year 1900 ...
Strong electrolyte. In chemistry, a strong electrolyte is a solute that completely, or almost completely, ionizes or dissociates in a solution. These ions are good conductors of electric current in the solution. Originally, a "strong electrolyte" was defined as a chemical compound that, when in aqueous solution, is a good conductor of electricity.
Electrolyte. An electrolyte is a substance that conducts electricity through the movement of ions, but not through the movement of electrons. [1][2][3] This includes most soluble salts, acids, and bases, dissolved in a polar solvent like water. Upon dissolving, the substance separates into cations and anions, which disperse uniformly throughout ...
The SI unit of electrical resistivity is the ohm - metre (Ω⋅m). [1][2][3] For example, if a 1 m3 solid cube of material has sheet contacts on two opposite faces, and the resistance between these contacts is 1 Ω, then the resistivity of the material is 1 Ω⋅m. Electrical conductivity (or specific conductance) is the reciprocal of ...
Wilhelm Ostwald ’s dilution law is a relationship proposed in 1888 [1] between the dissociation constant Kd and the degree of dissociation α of a weak electrolyte. The law takes the form [2] Where the square brackets denote concentration, and c0 is the total concentration of electrolyte. Using , where is the molar conductivity at ...
The Debye–Hückel theory was proposed by Peter Debye and Erich Hückel as a theoretical explanation for departures from ideality in solutions of electrolytes and plasmas. [1] It is a linearized Poisson–Boltzmann model, which assumes an extremely simplified model of electrolyte solution but nevertheless gave accurate predictions of mean activity coefficients for ions in dilute solution.
Supporting electrolyte is also sometimes referred to as background electrolyte, inert electrolyte, or inactive electrolyte. Supporting electrolytes are widely used in electrochemical measurements when control of electrode potentials is required. This is done to increase the conductivity of the solution (to practically eliminate the so-called IR ...