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Dichloromethane (DCM, methylene chloride, or methylene bichloride) is an organochlorine compound with the formula C H 2 Cl 2. This colorless, volatile liquid with a chloroform-like, sweet odor is widely used as a solvent. Although it is not miscible with water, it is slightly polar, and miscible with many organic solvents. [12]
A simple Lewis model also does not account for the phenomenon of aromaticity. For instance, Lewis structures do not offer an explanation for why cyclic C 6 H 6 (benzene) experiences special stabilization beyond normal delocalization effects, while C 4 H 4 (cyclobutadiene) actually experiences a special destabilization.
1,2-Dichloroethylene or 1,2-DCE is the name for a pair of organochlorine compounds with the molecular formula C 2 H 2 Cl 2.The two compounds are isomers, each being colorless liquids with a sweet odor.
Dichlorocarbene is an intermediate in the carbylamine reaction. In this conversion, a dichloromethane solution of a primary amine is treated with chloroform and aqueous sodium hydroxide in the presence of catalytic amount of the phase-transfer catalyst. Illustrative is the synthesis of tert-butyl isocyanide: [7]
1,1-Dichloroethylene, commonly called vinylidene chloride or 1,1-DCE, is an organochloride with the molecular formula CCl 2 CH 2.It is a colorless liquid with a sharp odor. Like most chlorocarbons, it is poorly soluble in water but soluble in organic solvents. 1,1-DCE was the precursor to the original clingwrap, Saran, for food, but this application has been phased
6 Structure and properties data. ... Please find below supplementary chemical data about dichloromethane. ... log 10 of Dichloromethane vapor pressure. Uses formula: ...
The compound is popularly used for palladium-catalyzed coupling reactions, [2] [3] such as the Buchwald–Hartwig amination [4] and the reductive homocoupling of aryl halides. [5] Examples of Buchwald-Hartwig aminations using second generation catalysts including [(dppf)PdCl 2]
Deuterated dichloromethane (CD 2 Cl 2 or C 2 H 2 Cl 2) [a] is a form (isotopologue) of dichloromethane (DCM, CH 2 Cl 2) in which the hydrogen atoms (H) are deuterium (heavy hydrogen) (2 H or D). [2] Deuterated DCM is not a common solvent used in NMR spectroscopy as it is expensive compared to deuterated chloroform .