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II:106 Although Bohr's model would also rely on just the electron to explain the spectrum, he did not assume an electrodynamical model for the atom. The other important advance in the understanding of atomic spectra was the Rydberg–Ritz combination principle which related atomic spectral line frequencies to differences between 'terms ...
Calculations based on the Bohr–Sommerfeld model were able to accurately explain a number of more complex atomic spectral effects. For example, up to first-order perturbations, the Bohr model and quantum mechanics make the same predictions for the spectral line splitting in the Stark effect. At higher-order perturbations, however, the Bohr ...
The Bohr model worked well for hydrogen and ionized single-electron helium, which impressed Einstein [56] [57] but could not explain more complex elements. By 1919, Bohr was moving away from the idea that electrons orbited the nucleus and developed heuristics to describe them.
The model's key success lay in explaining the Rydberg formula for the spectral emission lines of atomic hydrogen by using the transitions of electrons between orbits. [24]: 276 While the Rydberg formula had been known experimentally, it did not gain a theoretical underpinning until the Bohr model was introduced. Not only did the Bohr model ...
Complementarity as a physical model derives from Niels Bohr's 1927 presentation in Como, Italy, at a scientific celebration of the work of Alessandro Volta 100 years previous. [4]: 103 Bohr's subject was complementarity, the idea that measurements of quantum events provide complementary information through seemingly contradictory results. [5]
The current theoretical model of the atom involves a dense nucleus surrounded by a probabilistic "cloud" of electrons. Atomic theory is the scientific theory that matter is composed of particles called atoms.
This model, which became known as the Bohr–Sommerfeld model, allowed the orbits of the electron to be ellipses instead of circles, and introduced the concept of quantum degeneracy. The theory would have correctly explained the Zeeman effect, except for the issue of electron spin. Sommerfeld's model was much closer to the modern quantum ...
The model of the atom, first proposed by Niels Bohr in 1913, relied on a single quantum number. Together with Bohr's constraint that radiation absorption is not classical, it was able to explain the Balmer series portion of Rydberg's atomic spectrum formula. [3]