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Dark green crystals of nickelocene, sublimed and freshly deposited on a cold finger Sublimation of iodine. Sublimation is the transition of a substance directly from the solid to the gas state, without passing through the liquid state. [1] The verb form of sublimation is sublime, or less preferably, sublimate. [2]
In thermodynamics, the enthalpy of sublimation, or heat of sublimation, is the heat required to sublimate (change from solid to gas) one mole of a substance at a given combination of temperature and pressure, usually standard temperature and pressure (STP). It is equal to the cohesive energy of the solid.
Conditions are so chosen that the solid volatilizes and condenses as a purified compound on a cooled surface, leaving the non-volatile residual impurities or solid products behind. The form of the cooled surface often is a so-called cold finger which for very low-temperature sublimation may actually be cryogenically cooled.
This is an accepted version of this page This is the latest accepted revision, reviewed on 25 February 2025. This article is about the chemical element. For other uses, see Iodine (disambiguation). Chemical element with atomic number 53 (I) Iodine, 53 I Iodine Pronunciation / ˈ aɪ ə d aɪ n, - d ɪ n, - d iː n / (EYE -ə-dyne, -din, -deen) Appearance lustrous metallic gray solid ...
A typical phase diagram.The solid green line applies to most substances; the dashed green line gives the anomalous behavior of water. In thermodynamics, the triple point of a substance is the temperature and pressure at which the three phases (gas, liquid, and solid) of that substance coexist in thermodynamic equilibrium. [1]
These tables list values of molar ionization energies, measured in kJ⋅mol −1.This is the energy per mole necessary to remove electrons from gaseous atoms or atomic ions.
The enthalpy of atomization of an elemental solid is exactly the same as the enthalpy of sublimation for any elemental solid that becomes a monatomic gas upon evaporation. When a diatomic element is converted to gaseous atoms, only half a mole of molecules will be needed, as the standard enthalpy change is based purely on the production of one ...
Sublimation or sublimate may refer to: Sublimation, by Canvas Solaris, 2004; Sublimation (phase transition), directly from the solid to the gas phase; Sublimation (psychology), a mature type of defense mechanism; Sublimate of mercury, or Mercury(II) chloride; Volcanic sublimate, a product of deposition from vapors around volcanic vents