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Values are given in terms of temperature necessary to reach the specified pressure. Valid results within the quoted ranges from most equations are included in the table for comparison. A conversion factor is included into the original first coefficients of the equations to provide the pressure in pascals (CR2: 5.006, SMI: -0.875).
This is illustrated in the vapor pressure chart (see right) that shows graphs of the vapor pressures versus temperatures for a variety of liquids. [7] At the normal boiling point of a liquid, the vapor pressure is equal to the standard atmospheric pressure defined as 1 atmosphere, [ 1 ] 760 Torr, 101.325 kPa, or 14.69595 psi.
The boiling point of water is the temperature at which the saturated vapor pressure equals the ambient pressure. Water supercooled below its normal freezing point has a higher vapor pressure than that of ice at the same temperature and is, thus, unstable. Calculations of the (saturation) vapor pressure of water are commonly used in meteorology.
In honour of Torricelli, the torr was defined as a unit of pressure equal to one millimeter of mercury at 0 °C. However, since the acceleration due to gravity – and thus the weight of a column of mercury – is a function of elevation and latitude (due to the rotation and non- sphericity of the Earth), this definition is imprecise and varies ...
ρ of vapor Δ vap H: The table above gives properties of the vapor–liquid equilibrium of anhydrous ammonia at various temperatures. The second column is vapor pressure in kPa. The third column is the density of the liquid phase. The fourth column is the density of the vapor. The fifth column is the heat of vaporization needed to convert one ...
of formation, Δ f H o solid? kJ/mol Standard molar entropy, S o solid? J/(mol K) Heat capacity, c p? J/(mol K) Liquid properties Std enthalpy change of formation, Δ f H o liquid –271.2 kJ/mol Standard molar entropy, S o liquid: 253.5 J/(mol K) Enthalpy of combustion, Δ c H o –2726.3 kJ/mol Heat capacity, c p: 172.0 J/(mol K) Gas ...
of formation, Δ f H o solid? kJ/mol Standard molar entropy, S o solid? J/(mol K) Heat capacity, c p? J/(mol K) Liquid properties Std enthalpy change of formation, Δ f H o liquid-147.6 kJ/mol Standard molar entropy, S o liquid: 229.7 J/(mol K) Heat capacity, c p: 132.42 J/(mol K) –262 °C to –3 °C Gas properties Std enthalpy change of ...
of formation, Δ f H o solid? kJ/mol Standard molar entropy, S o solid? J/(mol K) Heat capacity, c p: 0.212 J/(mol K) at −200°C Liquid properties Std enthalpy change of formation, Δ f H o liquid: −318.2 kJ/mol Standard molar entropy, S o liquid: 180 J/(mol K) Heat capacity, c p: 2.68 J/(gK) at 20°C-25°C Gas properties Std enthalpy ...