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The Antoine equation is a class of semi-empirical correlations describing the relation between vapor pressure and temperature for pure substances. The Antoine equation is derived from the Clausius–Clapeyron relation. The equation was presented in 1888 by the French engineer Louis Charles Antoine (1825–1897). [1]
VLE of the mixture of chloroform and methanol plus NRTL fit and extrapolation to different pressures. The non-random two-liquid model [1] (abbreviated NRTL model) is an activity coefficient model introduced by Renon and Prausnitz in 1968 that correlates the activity coefficients of a compound with its mole fractions in the liquid phase concerned.
This page provides supplementary chemical data on toluene. MSDS sheets. Structure and properties. Structure and properties Index of refraction, n D: 1.4969 at 20 °C ...
The Antoine equation [3] [4] is a pragmatic mathematical expression of the relation between the vapor pressure and the temperature of pure liquid or solid substances. It is obtained by curve-fitting and is adapted to the fact that vapor pressure is usually increasing and concave as a function of temperature. The basic form of the equation is:
The Dortmund Data Bank [1] (short DDB) is a factual data bank for thermodynamic and thermophysical data. Its main usage is the data supply for process simulation where experimental data are the basis for the design, analysis, synthesis, and optimization of chemical processes.
where is the activity coefficient, P i is the partial pressure and P is the pressure. The values of the ratio K i are correlated empirically or theoretically in terms of temperature, pressure and phase compositions in the form of equations, tables or graph such as the DePriester charts. [5]
The following table lists the Van der Waals constants (from the Van der Waals equation) for a number of common gases and volatile liquids. [ 1 ] To convert from L 2 b a r / m o l 2 {\displaystyle \mathrm {L^{2}bar/mol^{2}} } to L 2 k P a / m o l 2 {\displaystyle \mathrm {L^{2}kPa/mol^{2}} } , multiply by 100.
Toluene (/ ˈ t ɒ l. j u iː n /), also known as toluol (/ ˈ t ɒ l. j u. ɒ l , - ɔː l , - oʊ l / ), is a substituted aromatic hydrocarbon [ 15 ] with the chemical formula C 6 H 5 CH 3 , often abbreviated as PhCH 3 , where Ph stands for the phenyl group.