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Tantalum pentoxide, also known as tantalum(V) oxide, is the inorganic compound with the formula Ta 2 O 5. It is a white solid that is insoluble in all solvents but is attacked by strong bases and hydrofluoric acid. Ta 2 O 5 is an inert material with a high refractive index and low absorption (i.e. colourless), which makes it useful for coatings ...
A typical tantalum capacitor is a chip capacitor and consists of tantalum powder pressed and sintered into a pellet as the anode of the capacitor, with the oxide layer of tantalum pentoxide as a dielectric, and a solid manganese dioxide electrolyte as the cathode.
Tantalum electrolytic capacitors exploit the tendency of tantalum to form a protective oxide surface layer, using tantalum powder, pressed into a pellet shape, as one "plate" of the capacitor, the oxide as the dielectric, and an electrolytic solution or conductive solid as the other "plate".
Tantalum(V) oxide films have a variety of applications including as optical films with refractive indices as high as 2.039 [16] and as a thin-film dielectric material in dynamic random access memory and semiconductor field-effect transistors. [12] The approach chosen for preparation of these materials is determined by the desired properties.
By applying a positive voltage to the above-mentioned anode material in an electrolytic bath an oxide barrier layer with a thickness corresponding to the applied voltage will be formed (formation). This oxide layer acts as the dielectric in an electrolytic capacitor. The properties of these oxide layers are given in the following table:
Characteristics of the different oxide layers in aluminium, tantalum and niobium electrolytic capacitors [19] [20] Anode-material Dielectric Oxide structure Relative permittivity Breakdown voltage (V/μm) Electric layer thickness (nm/V) Tantalum: Tantalum pentoxide Ta 2 O 5: amorphous: 27: 625: 1.6 Aluminum: Aluminium oxide Al 2 O 3: amorphous ...
The relative permittivity (in older texts, dielectric constant) is the permittivity of a material expressed as a ratio with the electric permittivity of a vacuum. A dielectric is an insulating material, and the dielectric constant of an insulator measures the ability of the insulator to store electric energy in an electrical field.
The capacitor typically consists of a sintered tantalum sponge acting as the anode, a manganese dioxide cathode, and a dielectric layer of tantalum pentoxide created on the tantalum sponge surface by anodizing. It may happen that the tantalum oxide layer has weak spots that undergo dielectric breakdown during a voltage spike.