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The procedure involves first preparing a platinum nitrate which is then heated to expel nitrogen oxides. [3] H 2 PtCl 6 + 6 NaNO 3 → Pt(NO 3) 4 + 6 NaCl (aq) + 2 HNO 3 Pt(NO 3) 4 → PtO 2 + 4 NO 2 + O 2. The resulting brown cake is washed with water to free it from nitrates. The catalyst can either be used as is or dried and stored in a ...
When heated to 150–180 °C, it decomposes with autooxidation to plutonium (VI) with the formation of plutonyl nitrate (PuO 2 (NO 3) 2).Upon evaporation of concentrated nitric acid solutions of plutonium nitrate and alkali metal nitrates, double nitrates of the composition M 2 [Pu(NO 3) 6] are formed, where M = Cs +, Rb +, K +, Tl +, NH 4 +, analogous to ceric ammonium nitrate.
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The title complex is one of several platinum ammine complexes. Hexaammineplatinum(IV) chloride; Trichlorotriammineplatinum(IV) chloride [2] cis-Tetrachlorodiammineplatinum(IV) [3] trans-Tetrachlorodiammineplatinum(IV) (RN 16986-23-5) [3]
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Lead(II,IV) oxide – Pb 3 O 4; Lead(IV) oxide – PbO 2; Lead(IV) sulfide – PbS 2; Lead hydrogen arsenate – PbHAsO 4; Lead styphnate – C 6 HN 3 O 8 Pb; Lead tetrachloride – PbCl 4; Lead tetrafluoride – PbF 4; Lead tetroxide – Pb 3 O 4 [205] Lead titanate – PbTiO 3; Lead zirconate titanate – Pb[Ti x Zr 1−x]O 3 (e.g., x = 0.52 ...
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Ammonium hexachloroplatinate is used in platinum plating. Heating (NH 4) 2 [PtCl 6] under a stream of hydrogen at 200 °C produces platinum sponge. Treating this with chlorine gives H 2 [PtCl 6]. [2] Ammonium hexachloroplatinate decomposes to yield platinum sponge when heated to high temperatures: [2] [5] 3(NH 4) 2 PtCl 6 → 3Pt(s) + 2NH 4 Cl ...
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