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Lithium, the lightest of the alkali metals, is the only alkali metal which reacts with nitrogen at standard conditions, and its nitride is the only stable alkali metal nitride. Nitrogen is an unreactive gas because breaking the strong triple bond in the dinitrogen molecule (N 2 ) requires a lot of energy.
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The alkali metals (lithium, sodium, potassium, rubidium, caesium, and francium) are the most homogeneous column of elements in the periodic table, exhibiting very clear periodic trends. All of them are soft and extremely reactive metals, readily giving up their sole valence electron to form cations.
Rieke metals are usually prepared by a reduction of an anhydrous metal chloride with an alkali metal, in a suitable solvent. [4] [3] For example, Rieke magnesium can be prepared from magnesium chloride with potassium as the reductant: [5] [6] [4] MgCl 2 + 2 K → Mg + 2 KCl. Rieke originally described three general procedures:
The profit made upon the chlorine produced has to make up for the loss on the alkali. [2] The ammonia-soda process was first patented on 30 June 1838 by Harrison Gray Dyar and John Hemming, [3] [4] who carried it out on an experimental scale in Whitechapel. Many attempts were soon after made in the same direction, both in England and on the ...
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NaK containing 40% to 90% potassium by mass is liquid at room temperature.The eutectic mixture consists of 77% potassium and 23% sodium by mass (NaK-77), and it is a liquid from −12.6 to 785 °C (9.3 to 1,445.0 °F), and has a density of 0.866 g/cm 3 at 21 °C (70 °F) and 0.855 g/cm 3 at 100 °C (212 °F), making it less dense than water. [3]
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