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tert-Butyl alcohol is deprotonated with a strong base to give the alkoxide. Particularly common is potassium tert-butoxide, which is prepared by treating tert-butanol with potassium metal. [8] K + t-BuOH → t-BuO − K + + 1 / 2 H 2. The tert-butoxide is a strong, non-nucleophilic base in organic chemistry.
tert-Butylbenzene is an organic compound classified as an aromatic hydrocarbon. Its structure consists of a benzene ring substituted with a tert -butyl group . It is a flammable colorless liquid which is nearly insoluble in water but miscible with organic solvents.
The effect of the tert-butyl group on the progress of a chemical reaction is called the Thorpe–Ingold effect illustrated in the Diels-Alder reaction below. Compared to a hydrogen substituent, the tert-butyl substituent accelerates the reaction rate by a factor of 240. [2] tert-Butyl effect. The tert-butyl effect is an example of steric hindrance.
Pages in category "Tert-butyl compounds" The following 200 pages are in this category, out of approximately 203 total. This list may not reflect recent changes .
Butanol (also called butyl alcohol) is a four-carbon alcohol with a formula of C 4 H 9 O H, which occurs in five isomeric structures (four structural isomers), from a straight-chain primary alcohol to a branched-chain tertiary alcohol; [1] all are a butyl or isobutyl group linked to a hydroxyl group (sometimes represented as BuOH, sec-BuOH, i-BuOH, and t-BuOH).
P 4-t-Bu is a readily accessible chemical from the group of neutral, peralkylated sterically hindered polyaminophosphazenes, which are extremely strong bases but very weak nucleophiles, with the formula (CH 3) 3 C−N=P(−N=P(−N(CH 3) 2) 3) 3. "t-Bu" stands for tert-butyl (CH 3) 3 C –. "P 4" stands for the fact that this molecule has 4 ...
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The molecular formula C 4 H 10 O may refer to: Butanols. 1-Butanol (n-Butanol) 2-Butanol (sec-Butanol) Isobutanol (2-methylpropan-1-ol) tert-Butyl alcohol (tert-Butanol, 2-methylpropanol) Ethers: Diethyl ether (ethoxyethane) Methyl propyl ether (methoxypropane, 1-methoxypropane) Methyl isopropyl ether or isopropyl methyl ether (2-methoxypropane)