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Boiling point (°C) K b (°C⋅kg/mol) Freezing point (°C) K f (°C⋅kg/mol) Data source; ... Acetic Anhydride: 139.0 [6] Ethylene Dichloride: 1.25 83.5 −35 [7 ...
This page contains tables of azeotrope data for various binary and ternary mixtures of solvents. The data include the composition of a mixture by weight (in binary azeotropes, when only one fraction is given, it is the fraction of the second component), the boiling point (b.p.) of a component, the boiling point of a mixture, and the specific gravity of the mixture.
The high reactivity of thiophene toward sulfonation is the basis for the separation of thiophene from benzene, which are difficult to separate by distillation due to their similar boiling points (4 °C difference at ambient pressure). Like benzene, thiophene forms an azeotrope with ethanol.
Because acetic anhydride is not stable in water, the conversion is conducted under anhydrous conditions. To a decreasing extent, acetic anhydride is also prepared by the reaction of ketene with acetic acid at 45–55 °C and low pressure (0.05–0.2 bar). [8] H 2 C=C=O + CH 3 COOH → (CH 3 CO) 2 O (ΔH = −63 kJ/mol)
This is a list of the various reported boiling points for the elements, with recommended values to be used elsewhere on Wikipedia. For broader coverage of this topic, see Boiling point . Boiling points, Master List format
Gas properties Std enthalpy change of formation Δ f H o gas –438.1 kJ/mol Standard molar entropy S o gas: 282.84 J/(mol K) Heat capacity c p: 63.4 J/(mol K) van der Waals' constants [2] a = 1782.3 L 2 kPa/mol 2 b = 0.1068 liter per mole
Both unsubstituted and substituted tetrahydrothiophenes are reported to occur in nature. For example, tetrahydrothiophene occurs as a volatile from Eruca sativa Mill. . (salad rocket) [5] while monocyclic substituted tetrahydrothiophenes have been isolated from Allium fistulosum 'Kujou', [6] Allium sativum (garlic), [7] Allium cepa (onion), [8] Allium schoenoprasum (chives), [9] and Salacia ...
In the laboratory, it can be easily synthesized from anthranilic acid and acetic anhydride. N-Acetylanthranilic acid exhibits triboluminescence when crushed. [5] The fractured crystals have large electrical potentials between areas of high and low charge.