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Temperature-dependency of the heats of vaporization for water, methanol, benzene, and acetone. In thermodynamics, the enthalpy of vaporization (symbol ∆H vap), also known as the (latent) heat of vaporization or heat of evaporation, is the amount of energy that must be added to a liquid substance to transform a quantity of that substance into a gas.
Vaporization (or vapo(u)risation) of an element or compound is a phase transition from the liquid phase to vapor. [1] There are two types of vaporization: evaporation and boiling . Evaporation is a surface phenomenon , whereas boiling is a bulk phenomenon (a phenomenon in which the whole object or substance is involved in the process).
L is the latent heat of vaporization at the temperature T, T C is the critical temperature, L 0 is the parameter that is equal to the heat of vaporization at zero temperature (T → 0), tanh is the hyperbolic tangent function. This equation was obtained in 1955 by Yu. I. Shimansky, at first empirically, and later derived theoretically.
Latent heat can be understood as hidden energy which is supplied or extracted to change the state of a substance without changing its temperature or pressure. This includes the latent heat of fusion (solid to liquid), the latent heat of vaporization (liquid to gas) and the latent heat of sublimation (solid to gas). [1] [2]
For a liquid–gas transition, is the molar latent heat (or molar enthalpy) of vaporization; for a solid–gas transition, is the molar latent heat of sublimation. If the latent heat is known, then knowledge of one point on the coexistence curve , for instance (1 bar, 373 K) for water, determines the rest of the curve.
where P 1, P 2 are the vapor pressures at temperatures T 1, T 2 respectively, ΔH vap is the enthalpy of vaporization, and R is the universal gas constant. The rate of evaporation in an open system is related to the vapor pressure found in a closed system. If a liquid is heated, when the vapor pressure reaches the ambient pressure the liquid ...
Water has a very high specific heat capacity of 4184 J/(kg·K) at 20 °C (4182 J/(kg·K) at 25 °C) —the second-highest among all the heteroatomic species (after ammonia), as well as a high heat of vaporization (40.65 kJ/mol or 2257 kJ/kg at the normal boiling point), both of which are a result of the extensive hydrogen bonding between its ...
Another definition of the LHV is the amount of heat released when the products are cooled to 150 °C (302 °F). This means that the latent heat of vaporization of water and other reaction products is not recovered. It is useful in comparing fuels where condensation of the combustion products is impractical, or heat at a temperature below 150 ...