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Phenol reacts with dilute nitric acid at room temperature to give a mixture of 2-nitrophenol and 4-nitrophenol while with concentrated nitric acid, additional nitro groups are introduced, e.g. to give 2,4,6-trinitrophenol. Friedel Crafts alkylations of phenol and its derivatives often proceed without catalysts. Alkylating agents include alkyl ...
This Wikipedia page provides a comprehensive list of boiling and freezing points for various solvents.
The Gmelin rare earths handbook lists 1522 °C and 1550 °C as two melting points given in the literature, the most recent reference [Handbook on the chemistry and physics of rare earths, vol.12 (1989)] is given with 1529 °C.
Phenolic resins are also used for making exterior plywood commonly known as weather and boil proof (WBP) plywood because phenolic resins have no melting point but only a decomposing point in the temperature zone of 220 °C (428 °F) and above. Phenolic resin is used as a binder in loudspeaker driver suspension components which are made of cloth.
Phenol is readily alkylated at the ortho positions using alkenes in the presence of a Lewis acid such as aluminium phenoxide: [citation needed] CH 2 =CR 2 + C 6 H 5 OH → R 2 CHCH 2 -2-C 6 H 4 OH More than 100,000 tons of tert-butyl phenols are produced annually (year: 2000) in this way, using isobutylene (CH 2 =CMe 2 ) as the alkylating agent.
Bakelite was produced for the first time in 1872 by Adolf von Baeyer, though its use as a commercial product was not considered at the time. [6]Leo Baekeland was already wealthy due to his invention of Velox photographic paper when he began to investigate the reactions of phenol and formaldehyde in his home laboratory.
Another method entails methylation of phenol with methanol over a solid acid catalyst, often comprising magnesium oxide or alumina. Temperatures above 300 °C are typical. Anisole converts to cresols under these conditions. [5] [6] Another isomer of cresol is called Benzyl alcohol, or alpha-cresol (α-cresol).
Melting point: 122.5 °C (252.5 °F; 395.6 K) ... phenol was obtained from coal as a co-product of coke ovens and the manufacture of gas ... and careful temperature ...