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LDPE has SPI resin ID code 4 Schematic of LDPE branching structure. Low-density polyethylene (LDPE) is a thermoplastic made from the monomer ethylene.It was the first grade of polyethylene, produced in 1933 by John C. Swallow and M.W Perrin who were working for Imperial Chemical Industries (ICI) using a high pressure process via free radical polymerization. [1]
LDPE and LLDPE have unique rheological or melt flow properties. LLDPE is less shear sensitive because of its narrower molecular weight distribution and shorter chain branching. During a shearing process, such as extrusion, LLDPE remains more viscous and, therefore, harder to process than an LDPE of equivalent melt index.
LDPE is defined by a density range of 0.910–0.940 g/cm 3. LDPE has a high degree of short- and long-chain branching, which means that the chains do not pack into the crystal structure as well. It has, therefore, less strong intermolecular forces as the instantaneous-dipole induced-dipole attraction is less.
List of some addition polymers and their uses ; Polymer Abbreviation Properties Uses Low-density polyethylene: LDPE: Chemically inert, flexible, insulator: Squeeze bottles, toys, flexible pipes, insulation cover (electric wires), six-pack rings, etc.
LDPE: mainly (70%) used for film. [1] Polypropylene: injection molding, fibers, and film. Compared to polyethylene, polypropylene is stiffer but less prone to breaking. It is less dense but shows more chemical resistance. [11] Synthetic base oil (by far the most used one): industrial and automotive lubricants. [12]
Basell completes start-up of the world's largest low-density polyethylene plant (LDPE) in Aubette, France, with a single line capacity of 320,000 tons per year. 2002: Lyondell increases interest in Equistar to 70.5 percent with acquisition of Occidental's share. 2004: Lyondell acquires Millennium Chemicals Inc.
This page was last edited on 14 January 2008, at 01:02 (UTC).; Text is available under the Creative Commons Attribution-ShareAlike 4.0 License; additional terms may apply.
One of the first examples of the problem concerned ESC of LDPE. The material was initially used in insulating electric cables, and cracking occurred due to the interaction of the insulation with oils. The solution to the problem lay in increasing the molecular weight of the polymer.
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