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These specific monosaccharide names have conventional three-letter abbreviations, like "Glu" for glucose and "Thr" for threose. Generally, a monosaccharide with n asymmetrical carbons has 2 n stereoisomers. The number of open chain stereoisomers for an aldose monosaccharide is larger by one than that of a ketose monosaccharide of the same length.
Metastable and kinetically persistent species or systems are not considered truly stable in chemistry. Therefore, the term chemically stable should not be used by chemists as a synonym of unreactive because it confuses thermodynamic and kinetic concepts. On the other hand, highly chemically unstable species tend to undergo exothermic unimolar ...
The darker more stable isotope region departs from the line of protons (Z) = neutrons (N), as the element number Z becomes larger. This is a list of chemical elements by the stability of their isotopes. Of the first 82 elements in the periodic table, 80 have isotopes considered to be stable. [1] Overall, there are 251 known stable isotopes in ...
The reason for glucose having the most stable cyclic form of all the aldohexoses is that its hydroxy groups (with the exception of the hydroxy group on the anomeric carbon of d-glucose) are in the equatorial position. Presumably, glucose is the most abundant natural monosaccharide because it is less glycated with proteins than other ...
This list is sorted by boiling point of gases in ascending order, but can be sorted on different values. "sub" and "triple" refer to the sublimation point and the triple point, which are given in the case of a substance that sublimes at 1 atm; "dec" refers to decomposition. "~" means approximately.
The aldohexose that is most important in biochemistry is D-glucose, which is the main "fuel" for metabolism in many living organisms. The 2-ketohexoses psicose, fructose and tagatose occur naturally as the D-isomers, whereas sorbose occurs naturally as the L-isomer. D-Sorbose is commonly used in the commercial synthesis of ascorbic acid. [10]
All chemical transformations pass through an unstable structure called the transition state, which is poised between the chemical structures of the substrates and products. The transition states for chemical reactions are proposed to have lifetimes near 10 −13 seconds, on the order of the time of a single bond vibration. No physical or ...
The general structure of a hemiacetal (left) and hemiketal (right). In organic chemistry, a hemiacetal is a functional group the general formula R 1 R 2 C(OH)OR, where R 1, R 2 is a hydrogen atom or an organic substituent.