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A spectator ion is an ion that exists both as a reactant and a product in a chemical equation of an aqueous solution. [1]For example, in the reaction of aqueous solutions of sodium carbonate and copper(II) sulfate:
Sodium carbonate (also known as washing soda, soda ash and soda crystals) is the inorganic compound with the formula Na 2 CO 3 and its various hydrates.All forms are white, odourless, water-soluble salts that yield alkaline solutions in water.
The concept of a reversible reaction was introduced by Claude Louis Berthollet in 1803, after he had observed the formation of sodium carbonate crystals at the edge of a salt lake [3] (one of the natron lakes in Egypt, in limestone): 2NaCl + CaCO 3 → Na 2 CO 3 + CaCl 2. He recognized this as the reverse of the familiar reaction Na 2 CO 3 ...
The ammonia from reaction (III) is recycled back to the initial brine solution of reaction (I). The sodium bicarbonate (NaHCO 3) precipitate from reaction (I) is then converted to the final product, sodium carbonate (washing soda: Na 2 CO 3), by calcination (160–230 °C), producing water and carbon dioxide as byproducts:
A white mixture of sucrose and sodium bicarbonate will eventually turn black and the snake will grow about 15–50 centimetres (5.9–19.7 in) long after it is lit. [4] Three chemical reactions occur when the snake is lit. Sodium bicarbonate breaks down into sodium carbonate, water vapor, and carbon dioxide: [2] 2 NaHCO 3 (s) → Na 2 CO 3 (s ...
The net reaction between an aldehyde (or an alpha-hydroxy-ketone) and the copper(II) ions in Benedict's solution may be written as: RCHO + 2 Cu 2+ + 5 OH − → RCOO − + Cu 2 O + 3 H 2 O. The hydroxide ions in the equation forms when sodium carbonate dissolves in water. With the citrate included, the reaction becomes:
Exceptions include barium sulfate, calcium sulfate (sparingly soluble), and lead(II) sulfate, where the 2+/2− pairing leads to high lattice energies. For similar reasons, most metal carbonates are not soluble in water. Some soluble carbonate salts are: sodium carbonate, potassium carbonate and ammonium carbonate.
What makes these compounds basic is that the conjugate base from the weak acid hydrolyzes to form a basic solution. In sodium carbonate, for example, the carbonate from the carbonic acid hydrolyzes to form a basic solution. The chloride from the hydrochloric acid in sodium chloride does not hydrolyze, though, so sodium chloride is not basic.
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