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Polarizability increases down on columns of the periodic table. [9] Likewise, larger molecules are generally more polarizable than smaller ones. Water is a very polar molecule, but alkanes and other hydrophobic molecules are more polarizable. Water with its permanent dipole is less likely to change shape due to an external electric field.
where μ is the electric dipole moment of the effectively polarized water molecule (2.35 D for the SPC/E model), μ 0 is the dipole moment of an isolated water molecule (1.85 D from experiment), and α i is an isotropic polarizability constant, with a value of 1.608 × 10 −40 F·m 2. Since the charges in the model are constant, this ...
An Ion of charge and a nonpolar molecule of polarizability . The Lifshitz theory can be expressed as an effective Hamaker constant in the van der Waals theory. Consider, for example, the interaction between an ion of charge Q {\textstyle Q} , and a nonpolar molecule with polarizability α 2 {\textstyle \alpha _{2}} at distance r {\textstyle r} .
London dispersion forces are also known as 'dispersion forces', 'London forces', or 'instantaneous dipole–induced dipole forces'. The strength of London dispersion forces is proportional to the polarizability of the molecule, which in turn depends on the total number of electrons and the area over which they are spread.
Dispersion of gravity waves on a fluid surface. Phase and group velocity divided by shallow-water phase velocity √ gh as a function of relative depth h / λ. Blue lines (A): phase velocity; Red lines (B): group velocity; Black dashed line (C): phase and group velocity √ gh valid in shallow water.
The self-diffusion coefficient of water has been experimentally determined with high accuracy and thus serves often as a reference value for measurements on other liquids. The self-diffusion coefficient of neat water is: 2.299·10 −9 m 2 ·s −1 at 25 °C and 1.261·10 −9 m 2 ·s −1 at 4 °C. [2]
For example, nine of the nineteen L-amino acids naturally occurring in proteins are, despite the L- prefix, actually dextrorotary (at a wavelength of 589 nm), and D-fructose is sometimes called "levulose" because it is levorotary. The D- and L- prefixes describe the molecule as a whole, as do the (+) and (−) prefixes for optical rotation.
In fluid dynamics, eddy diffusion, eddy dispersion, or turbulent diffusion is a process by which fluid substances mix together due to eddy motion. These eddies can vary widely in size, from subtropical ocean gyres down to the small Kolmogorov microscales , and occur as a result of turbulence (or turbulent flow).