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Plots of pressure vs temperature for three different gas samples extrapolated to absolute zero. The ideal gas law is based on observed empirical relationships between pressure (p), volume (V), and temperature (T), and was recognized long before the kinetic theory of gases was developed (see Boyle's and Charles's laws). The ideal gas law states ...
Thermodynamic temperature is a quantity defined in thermodynamics as distinct from kinetic theory or statistical mechanics.. Historically, thermodynamic temperature was defined by Lord Kelvin in terms of a macroscopic relation between thermodynamic work and heat transfer as defined in thermodynamics, but the kelvin was redefined by international agreement in 2019 in terms of phenomena that are ...
The heat content of an ideal gas is independent of pressure (or volume), but the heat content of real gases varies with pressure, hence the need to define the state for the gas (real or ideal) and the pressure. Note that for some thermodynamic databases such as for steam, the reference temperature is 273.15 K (0 °C).
Q H is the heat put into the system (heat energy entering the system), T C is the absolute temperature of the cold reservoir, and; T H is the absolute temperature of the hot reservoir. A corollary to Carnot's theorem states that: All reversible engines operating between the same heat reservoirs are equally efficient.
Absolute zero is the lowest limit of the thermodynamic temperature scale; a state at which the enthalpy and entropy of a cooled ideal gas reach their minimum value. The fundamental particles of nature have minimum vibrational motion, retaining only quantum mechanical, zero-point energy -induced particle motion.
Turn the heat down when you're away. But setting your thermostat to a specific temperature and never changing it won't be good for your heating bills. Though about 70 degrees is ideal, it's unwise ...
A reversible heat engine with a low efficiency delivers more heat (energy) to the hot reservoir for a given amount of work (energy) to this engine when it is being driven as a heat pump. All these mean that heat can transfer from cold to hot places without external work, and such a heat transfer is impossible by the second law of thermodynamics.
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