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Zinc iodide is often used as an x-ray opaque penetrant in industrial radiography to improve the contrast between the damage and intact composite. [8] [9]United States patent 4,109,065 [10] describes a rechargeable aqueous zinc-halogen cell that includes an aqueous electrolytic solution containing a zinc salt selected from the class consisting of zinc bromide, zinc iodide, and mixtures thereof ...
Zn 2+ is a class A acceptor in the classification of Ahrland, Chatt and Davies, [16] and so forms stronger complexes with the first-row donor atoms oxygen or nitrogen than with second-row sulfur or phosphorus. In terms of HSAB theory Zn 2+ is a hard acid. In aqueous solution an octahedral complex, [Zn(H 2 O) 6] 2+ is the predominant species. [17]
The compound appears to be highly unstable but can react with alkenes to give halogenated products. [ 7 ] Radical iodine oxide (IO), iodine dioxide (IO 2 ), collectively referred to as I x O y and iodine tetroxide ((I 2 O 4 ) all possess significant and interconnected atmospheric chemistry.
Iodine dioxide is a binary inorganic compound of iodine and oxygen with the chemical formula IO 2. [1] [2] Only stable as a dilute gas, [3] this compound is one of many iodine oxides, [4] [5] and "iodine dioxide" is sometimes used to describe its formal dimer, the salt diiodine tetroxide (I 2 O 4, [IO] + [IO 3] −).
Iodine forms all three possible diatomic interhalogens, a trifluoride and trichloride, as well as a pentafluoride and, exceptionally among the halogens, a heptafluoride. Numerous cationic and anionic derivatives are also characterised, such as the wine-red or bright orange compounds of ICl + 2 and the dark brown or purplish black compounds of I ...
Zn(CN) 2 is easy to make by combining aqueous solutions of cyanide and zinc ions, for example via the double replacement reaction between KCN and ZnSO 4: [5] ZnSO 4 + 2 KCN → Zn(CN) 2 + K 2 SO 4. For commercial applications, some effort is made to avoid halide impurities by using acetate salts of zinc: [5] [6] Zn(CH 3 COO) 2 + HCN → Zn(CN ...
Periodate (/ p ə ˈ r aɪ. ə d eɪ t / pə-RY-ə-dayt) is an anion composed of iodine and oxygen.It is one of a number of oxyanions of iodine and is the highest in the series, with iodine existing in oxidation state +7.
Zinc(I) compounds are very rare. The [Zn 2] 2+ ion is implicated by the formation of a yellow diamagnetic glass by dissolving metallic zinc in molten ZnCl 2. [62] The [Zn 2] 2+ core would be analogous to the [Hg 2] 2+ cation present in mercury(I) compounds. The diamagnetic nature of the ion confirms its dimeric structure. The first zinc(I ...