Search results
Results from the WOW.Com Content Network
2 As 2 O 3 + 3 S + 6 Br 2 → 4 AsBr 3 + 3 SO 2. Arsenic tribromide is a highly water soluble crystalline arsenic source for uses compatible with bromides and lower (acidic) pH. Most metal bromide compounds are water soluble for uses in water treatment, chemical analysis and in ultra high purity for certain crystal growth applications.
The main structure of chemical names according to IUPAC nomenclature. IUPAC nomenclature is a set of recommendations for naming chemical compounds and for describing chemistry and biochemistry in general. The International Union of Pure and Applied Chemistry (IUPAC) is the international authority on chemical nomenclature and terminology.
A demonstration of the reaction of the exothermic reaction of the strong Lewis acid (Al 2 Br 6) and strong Lewis base (H 2 O). Al 2 Br 6 dissociates readily to give the strong Lewis acid , AlBr 3 . Regarding the tendency of Al 2 Br 6 to dimerize , it is common for heavier main group halides to exist as aggregates larger than implied by their ...
It is somewhat soluble in water and readily evaporates into the air. Bromoform is the main trihalomethane produced in beachfront salt water swimming pools with concentrations as high as 1.2 ppm (parts per million). Concentrations in freshwater pools are 1000 times lower. [9] Occupational skin exposure limits are set at 0.5 ppm. [10]
As is expected, it may be prepared by reaction between phosphorus tribromide and acetic acid: [2] 3 CH 3 COOH + PBr 3 → 3 CH 3 COBr + H 3 PO 3. As usual for an acid halide, acetyl bromide hydrolyzes rapidly in water, forming acetic acid and hydrobromic acid. It also reacts with alcohols and amines to produce acetate esters and acetamides ...
[5] [6] In some cases, triphenylphosphine/Br 2 is superior to PBr 3. [7] The mechanism for a primary alcohol involves formation of a phosphorous ester (to form a good leaving group), followed by an S N 2 substitution. Because of the S N 2 substitution step, the reaction generally works well for primary and secondary alcohols, but fails for ...
As 2 O 3 + 6 HCl → 2 AsCl 3 + 3 H 2 O. It can also be prepared by chlorination of arsenic at 80–85 °C, but this method requires elemental arsenic. [4] 2 As + 3 Cl 2 → 2 AsCl 3. Arsenic trichloride can be prepared by the reaction of arsenic oxide and sulfur monochloride. This method requires simple apparatus and proceeds efficiently: [8]
Because acetic anhydride is not stable in water, the conversion is conducted under anhydrous conditions. To a decreasing extent, acetic anhydride is also prepared by the reaction of ketene with acetic acid at 45–55 °C and low pressure (0.05–0.2 bar). [8] H 2 C=C=O + CH 3 COOH → (CH 3 CO) 2 O (ΔH = −63 kJ/mol)