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Molar concentration or molarity is most commonly expressed in units of moles of solute per litre of solution. [1] For use in broader applications, it is defined as amount of substance of solute per unit volume of solution, or per unit volume available to the species, represented by lowercase : [2]
R is the ideal gas constant. M is the molar mass of the solvent. T b is boiling point of the pure solvent in kelvin. ΔH vap is the molar enthalpy of vaporization of the solvent. Through the procedure called ebullioscopy, a known constant can be used to calculate an unknown molar mass. The term ebullioscopy means "boiling measurement" in Latin.
The ideal gas equation can be rearranged to give an expression for the molar volume of an ideal gas: = = Hence, for a given temperature and pressure, the molar volume is the same for all ideal gases and is based on the gas constant: R = 8.314 462 618 153 24 m 3 ⋅Pa⋅K −1 ⋅mol −1, or about 8.205 736 608 095 96 × 10 −5 m 3 ⋅atm⋅K ...
For example, the blood/gas partition coefficient of a general anesthetic measures how easily the anesthetic passes from gas to blood. [5] Partition coefficients can also be defined when one of the phases is solid , for instance, when one phase is a molten metal and the second is a solid metal, [ 6 ] or when both phases are solids. [ 7 ]
The atmospheric pressure is roughly equal to the sum of partial pressures of constituent gases – oxygen, nitrogen, argon, water vapor, carbon dioxide, etc.. In a mixture of gases, each constituent gas has a partial pressure which is the notional pressure of that constituent gas as if it alone occupied the entire volume of the original mixture at the same temperature. [1]
If no bulk flow occurs in an element of length dx, the rates of diffusion of two ideal gases (of similar molar volume) A and B must be equal and opposite, that is =. The partial pressure of A changes by dP A over the distance dx. Similarly, the partial pressure of B changes dP B. As there is no difference in total pressure across the element ...
In simple words, we can say that the partial pressure of a gas in vapour phase is directly proportional to the mole fraction of a gas in solution. An example where Henry's law is at play is the depth-dependent dissolution of oxygen and nitrogen in the blood of underwater divers that changes during decompression, going to decompression sickness.
When expressed in percent, it is known as the mole percent or molar percentage (unit symbol %, sometimes "mol%", equivalent to cmol/mol for 10 −2). The mole fraction is called amount fraction by the International Union of Pure and Applied Chemistry (IUPAC) [ 1 ] and amount-of-substance fraction by the U.S. National Institute of Standards and ...