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For example, for the polymerization of ethylene, 93.6 kJ of energy are released per mole of monomer. [8] The manner in which polymerization is conducted is a highly evolved technology. Methods include emulsion polymerization, solution polymerization, suspension polymerization, and precipitation polymerization.
One of the key issues that have limited the performance of MIPs in practical applications so far is the lack of simple and robust methods to synthesize MIPs in the optimum formats required by the application. Chronologically, the first polymerization method encountered for MIP was based on "bulk" or solution polymerization.
RAFT polymerization today is mainly carried out by thiocarbonylthio chain transfer agents. It was first reported by Rizzardo et al. in 1998. [6] RAFT is one of the most versatile methods of controlled radical polymerization because it is tolerant of a very wide range of functionality in the monomer and solvent, including aqueous solutions. [7]
Example of chain polymerization: Radical polymerization of styrene, R. is initiating radical, P. is another polymer chain radical terminating the formed chain by radical recombination. Newer methods, such as plasma polymerization do not fit neatly into either category. Synthetic polymerization reactions may be carried out with or without a ...
However in step-growth polymerization the monomer is consumed very quickly to dimer, trimer and oligomer. The degree of polymerization increases steadily during the whole polymerization process. The type of polymerization of a given monomer usually depends on the functional groups present, and sometimes also on whether the monomer is linear or ...
Enzymatic polymerization is a potential area in polymer research, providing a sustainable and adaptable alternative to conventional polymerization processes. Its capacity to manufacture polymers with exact structures in mild circumstances opens up new possibilities for material design and application, helping to progress both research and industry.
Other methods of radical polymerization include the following: Template polymerization: In this process, polymer chains are allowed to grow along template macromolecules for the greater part of their lifetime. A well-chosen template can affect the rate of polymerization as well as the molar mass and microstructure of the daughter polymer.
Polymer characterization is the analytical branch of polymer science. The discipline is concerned with the characterization of polymeric materials on a variety of levels. The characterization typically has as a goal to improve the performance of the material.